Doubly N-fused porphyrin

Motoki Toganoh, Tomoyuki Kimura, Hidemitsu Uno, Hiroyuki Furuta

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

(Figure Presented) Are you N-fused? Doubly N-fused porphyrin (see picture; Br red, F green, N blue) exhibits exceptionally long-wavelength absorption for an 18π aromatic system (in excess of 1600 nm). The HOMO-LUMO energy gap of doubly N-fused porphyrin is extremely small for an [18]annulenic compound and results from endocyclic extension of the porphyrin π system.

Original languageEnglish
Pages (from-to)8913-8916
Number of pages4
JournalAngewandte Chemie - International Edition
Volume47
Issue number46
DOIs
Publication statusPublished - Nov 3 2008

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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