Doubly N-fused porphyrin

Motoki Toganoh, Tomoyuki Kimura, Hidemitsu Uno, Hiroyuki Furuta

    Research output: Contribution to journalArticlepeer-review

    42 Citations (Scopus)

    Abstract

    (Figure Presented) Are you N-fused? Doubly N-fused porphyrin (see picture; Br red, F green, N blue) exhibits exceptionally long-wavelength absorption for an 18π aromatic system (in excess of 1600 nm). The HOMO-LUMO energy gap of doubly N-fused porphyrin is extremely small for an [18]annulenic compound and results from endocyclic extension of the porphyrin π system.

    Original languageEnglish
    Pages (from-to)8913-8916
    Number of pages4
    JournalAngewandte Chemie - International Edition
    Volume47
    Issue number46
    DOIs
    Publication statusPublished - Nov 3 2008

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Chemistry(all)

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