Dynamic kinetic resolution in BINAP-ruthenium(II) catalyzed hydrogenation of 2-substituted 3-oxo carboxylic esters

M. Kitamura, T. Ohkuma, M. Tokunaga, R. Noyori

Research output: Contribution to journalArticle

92 Citations (Scopus)

Abstract

BINAP-Ru catalyzed hydrogenation allows efficient dynamic kinetic resolution of certain 2-substituted 3-oxo carboxylic esters having cyclic structures to lead to the alcoholic products in high enantiomeric and diastereomeric excesses.

Original languageEnglish
Pages (from-to)1-4
Number of pages4
JournalTetrahedron: Asymmetry
Volume1
Issue number1
DOIs
Publication statusPublished - 1990

Fingerprint

Ruthenium
ruthenium
Hydrogenation
hydrogenation
esters
Esters
Kinetics
kinetics
products
2-naphthol BINAP

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Dynamic kinetic resolution in BINAP-ruthenium(II) catalyzed hydrogenation of 2-substituted 3-oxo carboxylic esters. / Kitamura, M.; Ohkuma, T.; Tokunaga, M.; Noyori, R.

In: Tetrahedron: Asymmetry, Vol. 1, No. 1, 1990, p. 1-4.

Research output: Contribution to journalArticle

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