Dynamics Gradient of Polymer Chains near a Solid Interface

Hung K. Nguyen, Shin Sugimoto, Asuka Konomi, Manabu Inutsuka, Daisuke Kawaguchi, Keiji Tanaka

Research output: Contribution to journalArticle

Abstract

The relaxation dynamics of polyisoprene (PI) and nitrile butadiene rubber (NBR) chains at the SiO2 interface were directly probed as a function of distance from the SiO2 surface using time-resolved evanescent wave-induced fluorescence anisotropy, dielectric relaxation spectroscopy, and sum-frequency generation spectroscopy. We found the presence of the dynamics gradient of chains in the interfacial region with the SiO2 surface and tried to assign it to the two kinds of adsorbed chains, namely, loosely and strongly adsorbed, at the interface. The segmental relaxation of chains in the strongly adsorbed layer at the interface could be slower than that of bulk chains by more than 10 orders.

Original languageEnglish
Pages (from-to)1006-1011
Number of pages6
JournalACS Macro Letters
Volume8
Issue number8
DOIs
Publication statusPublished - Aug 20 2019

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Polymers
Spectroscopy
Nitriles
Polyisoprenes
Dielectric relaxation
Rubber
Butadiene
Anisotropy
Fluorescence
1,3-butadiene

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Dynamics Gradient of Polymer Chains near a Solid Interface. / Nguyen, Hung K.; Sugimoto, Shin; Konomi, Asuka; Inutsuka, Manabu; Kawaguchi, Daisuke; Tanaka, Keiji.

In: ACS Macro Letters, Vol. 8, No. 8, 20.08.2019, p. 1006-1011.

Research output: Contribution to journalArticle

Nguyen, Hung K. ; Sugimoto, Shin ; Konomi, Asuka ; Inutsuka, Manabu ; Kawaguchi, Daisuke ; Tanaka, Keiji. / Dynamics Gradient of Polymer Chains near a Solid Interface. In: ACS Macro Letters. 2019 ; Vol. 8, No. 8. pp. 1006-1011.
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