Eco-friendly molecular transformations catalyzed by a vitamin B 12 derivative with a visible-light-driven system

Keishiro Tahara, Yoshio Hisaeda

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

A new bio-inspired system composed of a vitamin B12 derivative and Rose Bengal, catalyzed the dehalogenations of various toxic alkyl halides such as 1,1-bis(4-chlorophenyl)-2,2,2-trichloroethane (DDT) via a noble-metal-free and visible-light-driven process. This system also catalyzed radical-involved organic reactions such as the 1,2-migration of acyl group via a tin-free process.

Original languageEnglish
Pages (from-to)558-561
Number of pages4
JournalGreen Chemistry
Volume13
Issue number3
DOIs
Publication statusPublished - Mar 1 2011

Fingerprint

Trichloroethanes
Dehalogenation
Rose Bengal
DDT
Tin
halide
Poisons
Vitamins
Vitamin B 12
Precious metals
vitamin
tin
Derivatives
metal

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Pollution

Cite this

Eco-friendly molecular transformations catalyzed by a vitamin B 12 derivative with a visible-light-driven system. / Tahara, Keishiro; Hisaeda, Yoshio.

In: Green Chemistry, Vol. 13, No. 3, 01.03.2011, p. 558-561.

Research output: Contribution to journalArticle

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