Effect of 3,4,9,10-perylenetetracarboxylic bisbenzimidazole (PTCBI) as well as bathocuproine (BCP) and Ag interlayer thickness on the performance of organic tandem solar cells

Yanqiong Zheng, Fang Yang, Chao Wang, Jing Zhang, William J. Potscavage, Bin Wei, Chihaya Adachi, Wenhong Pu, Changzhu Yang, Jianhua Zhang

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Firstly, multi-fold subphthalocyanine (SubPc) homo-tandem cells were fabricated. When complementary absorbing SubPc and chloroaluminum phthalocyanine (ClAlPc) were used to prepare tandem cells, both short circuit current (J SC ) and fill factor (FF) are significantly improved relative to the SubPc double tandem cell. 3,4,9,10-perylenetetracarboxylic bisbenzimidazole (PTCBI) as electron transporting layer (ETL) in the charge recombination zone (CRZ) achieves a much higher FF than bathocuproine (BCP) thus higher power conversion efficiency (η PCE ) in both the normal and reverse tandem cells, ascribed to the matched energy levels, very smooth film surface, and ohmic contact with Ag interlayer. The effect of Ag interlayer thickness was also investigated. Ultrathin Ag layer with isolated clusters is helpful for obtaining higher photocurrent in both PTCBI and BCP based CRZs, originating from a flatter interface, less optical loss, and a plasmonic effect induced absorption enhancement of C 60 in bottom subcell. By optical modeling for current matching, the performance of normal tandem cell is improved, exhibiting a high open circuit voltage of 1.80 V and an overall η PCE of 3.49%.

Original languageEnglish
Pages (from-to)179-185
Number of pages7
JournalSynthetic Metals
Volume221
DOIs
Publication statusPublished - Nov 1 2016

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Conversion efficiency
interlayers
Solar cells
solar cells
Optical losses
Ohmic contacts
Open circuit voltage
cells
Photocurrents
Short circuit currents
Electron energy levels
Electrons
short circuit currents
open circuit voltage
photocurrents
high voltages
electric contacts
energy levels
bis-benzimidazole
bathocuproine

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Effect of 3,4,9,10-perylenetetracarboxylic bisbenzimidazole (PTCBI) as well as bathocuproine (BCP) and Ag interlayer thickness on the performance of organic tandem solar cells. / Zheng, Yanqiong; Yang, Fang; Wang, Chao; Zhang, Jing; Potscavage, William J.; Wei, Bin; Adachi, Chihaya; Pu, Wenhong; Yang, Changzhu; Zhang, Jianhua.

In: Synthetic Metals, Vol. 221, 01.11.2016, p. 179-185.

Research output: Contribution to journalArticle

Zheng, Yanqiong ; Yang, Fang ; Wang, Chao ; Zhang, Jing ; Potscavage, William J. ; Wei, Bin ; Adachi, Chihaya ; Pu, Wenhong ; Yang, Changzhu ; Zhang, Jianhua. / Effect of 3,4,9,10-perylenetetracarboxylic bisbenzimidazole (PTCBI) as well as bathocuproine (BCP) and Ag interlayer thickness on the performance of organic tandem solar cells. In: Synthetic Metals. 2016 ; Vol. 221. pp. 179-185.
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abstract = "Firstly, multi-fold subphthalocyanine (SubPc) homo-tandem cells were fabricated. When complementary absorbing SubPc and chloroaluminum phthalocyanine (ClAlPc) were used to prepare tandem cells, both short circuit current (J SC ) and fill factor (FF) are significantly improved relative to the SubPc double tandem cell. 3,4,9,10-perylenetetracarboxylic bisbenzimidazole (PTCBI) as electron transporting layer (ETL) in the charge recombination zone (CRZ) achieves a much higher FF than bathocuproine (BCP) thus higher power conversion efficiency (η PCE ) in both the normal and reverse tandem cells, ascribed to the matched energy levels, very smooth film surface, and ohmic contact with Ag interlayer. The effect of Ag interlayer thickness was also investigated. Ultrathin Ag layer with isolated clusters is helpful for obtaining higher photocurrent in both PTCBI and BCP based CRZs, originating from a flatter interface, less optical loss, and a plasmonic effect induced absorption enhancement of C 60 in bottom subcell. By optical modeling for current matching, the performance of normal tandem cell is improved, exhibiting a high open circuit voltage of 1.80 V and an overall η PCE of 3.49{\%}.",
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AU - Yang, Fang

AU - Wang, Chao

AU - Zhang, Jing

AU - Potscavage, William J.

AU - Wei, Bin

AU - Adachi, Chihaya

AU - Pu, Wenhong

AU - Yang, Changzhu

AU - Zhang, Jianhua

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