Effect of a polybenzimidazole coating on carbon supports for ionomer content optimization in polymer electrolyte membrane fuel cells

Samindi Madhubha Jayawickrama, Dan Wu, Rei Nakayama, Shota Ishikawa, Xuanchen Liu, Gen Inoue, Tsuyohiko Fujigaya

Research output: Contribution to journalArticlepeer-review

Abstract

Optimizing the ionomer/carbon (I/C) ratio in the catalyst layer (CL) of polymer electrolyte membrane fuel cells (PEMFCs) is vital for maximizing PEMFC efficiency. In this study, the effect of the I/C ratio for a platinum (Pt) catalyst loaded on a polybenzimidazole (PBI)-coated Vulcan (Vulcan/PBI/Pt) is compared with a conventional Pt catalyst on Vulcan (Vulcan/Pt). Furthermore, this study determines that a CL comprising Vulcan/PBI/Pt with an I/C = 0.2 exhibits the highest maximum power density (750 mW cm−2), while that of a CL having Vulcan/Pt is calculated to be 610 mWcm−2 at I/C = 0.6. Effective interactions between ionomer and the PBI-coated Vulcan enables stable ionomer coating and high proton conductivity, even at very low I/C ratios. At such low I/C ratios, the O2 diffusion coefficient of Vulcan/PBI/Pt CL is improved by 51% when compared to Vulcan/Pt CL with an I/C = 0.6. Cross-sectional scanning electron microscopy images further reveal that Vulcan/PBI/Pt CLs possess better pore connectivity than those of Vulcan/Pt. Hence, it concludes that the proposed PBI coating approach is advantageous and significant breakthrough to fabricate highly efficient CLs by improving both proton conduction and O2 diffusion simultaneously with lower ionomer contents.

Original languageEnglish
Article number229855
JournalJournal of Power Sources
Volume496
DOIs
Publication statusPublished - Jun 1 2021

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

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