Effect of CO gas concentration on reduction rate of major mineral phase in sintered iron ore

Daisuke Noguchi, Ko-Ichiro Ohno, Takayuki Maeda, Kouki Nishioka, Masakata Shimizu

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

As a fundamental study for clarifying the reduction phenomena of iron ore sinter in blast furnace, iron oxide (H) and quaternary calcium ferrite (Cf) were prepared and these kinetic behaviors at the final stage of reduction with CO-CO2 gas mixture were studied. Reduction rate increased with increasing reduction temperature. Moreover, it increased with increasing partial pressure of CO gas. Difference of reduction rate caused by gas composition is much larger than reduction temperature. From comparisons of weight loss curves, reduction rate of H samples was faster than that of Cf samples under the same or similar conditions. Reduction reaction of H and Cf samples proceeded topochemically at higher temperature (≥1100°C), and didn't proceed topochemically at lower temperature (≤1 000°C). Besides, the reduction reaction of samples with CO rich gas proceeded more topochemically. Structure of iron layer in H samples was affected by temperature and gas composition. On the other hand, structure of iron layer in Cf samples was almost the same in all experimental conditions. Reduction data were analyzed based on one interface unreacted core model, and chemical reaction rate content kc and effective diffusion coefficient in product layer De were determined. The values of kc show Arrhenius-type temperature dependency, and were approximately same tendency except for Cf samples with near equilibriums gas compositions. The values of De of H samples show the temperature and gas composition dependencies, and that of Cf samples were approximately constant in all experimental conditions.

Original languageEnglish
Pages (from-to)570-575
Number of pages6
Journalisij international
Volume53
Issue number4
DOIs
Publication statusPublished - Jun 21 2013

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Iron ores
Carbon Monoxide
Minerals
Gases
Ferrite
Calcium
Temperature
Chemical analysis
Iron ore sinter
Iron
Blast furnaces
Iron oxides
Gas mixtures
Partial pressure
Reaction rates
Chemical reactions
Data reduction
Kinetics

All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Effect of CO gas concentration on reduction rate of major mineral phase in sintered iron ore. / Noguchi, Daisuke; Ohno, Ko-Ichiro; Maeda, Takayuki; Nishioka, Kouki; Shimizu, Masakata.

In: isij international, Vol. 53, No. 4, 21.06.2013, p. 570-575.

Research output: Contribution to journalArticle

Noguchi, Daisuke ; Ohno, Ko-Ichiro ; Maeda, Takayuki ; Nishioka, Kouki ; Shimizu, Masakata. / Effect of CO gas concentration on reduction rate of major mineral phase in sintered iron ore. In: isij international. 2013 ; Vol. 53, No. 4. pp. 570-575.
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