Effect of linear elongation on carbon nanotube and polyelectrolyte structures in pdms-supported nanocomposite LbL films

Johannes Frueh, Naotoshi Nakashima, Qiang He, Helmuth Möhwald

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Polyelectrolyte (PE) multilayer (PEM) thin films prepared by layer-by-layer self-assembly on flexible substrates are exposed to elongation in many fields of technology. Upon elongation, these types of films are showing interesting, but not understood, phenomena, such as controlled wetting, stimuliresponsive nanovalves, and lithography-free surface structuring. To investigate the mechanisms causing these interesting phenomena, we employed spectroscopic investigations of supported PEM films that were prepared from polystyrene sulfonate (PSS)-wrapped single-walled carbon nanotubes (SWNTs) or pyrene-labeled PSS (PSS-PY) and polydiallyldiammonium chloride. Our results show that the SWNTs agglomerated upon deposition into the PEM and showed a strong change in orientation upon uniaxial elongation of the PEM. Upon release of elongation, the resulting wrinkling pattern was changing its wavelength upon time, in the case of the SWNT-containing PEM. Fluorescence measurements of the PSS-PY in the PEM showed that the PEs changed their orientation due to constant mechanical force from elongation up to a time scale of 2 days after beginning the elongation. The results prove that elongated and released PEM films, until now considered static structures, possess strong kinetics, which has to be taken into account for their application.

Original languageEnglish
Pages (from-to)12257-12262
Number of pages6
JournalJournal of Physical Chemistry B
Volume116
Issue number40
DOIs
Publication statusPublished - Oct 11 2012

Fingerprint

Carbon Nanotubes
Nanocomposite films
Polyelectrolytes
elongation
Elongation
Carbon nanotubes
nanocomposites
carbon nanotubes
sulfonates
Multilayer films
Polystyrenes
polystyrene
Multilayers
Single-walled carbon nanotubes (SWCN)
wrinkling
Pyrene
pyrenes
Self assembly
Lithography
wetting

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Effect of linear elongation on carbon nanotube and polyelectrolyte structures in pdms-supported nanocomposite LbL films. / Frueh, Johannes; Nakashima, Naotoshi; He, Qiang; Möhwald, Helmuth.

In: Journal of Physical Chemistry B, Vol. 116, No. 40, 11.10.2012, p. 12257-12262.

Research output: Contribution to journalArticle

Frueh, Johannes ; Nakashima, Naotoshi ; He, Qiang ; Möhwald, Helmuth. / Effect of linear elongation on carbon nanotube and polyelectrolyte structures in pdms-supported nanocomposite LbL films. In: Journal of Physical Chemistry B. 2012 ; Vol. 116, No. 40. pp. 12257-12262.
@article{729cad28e0f8418cab4edb6d30050b54,
title = "Effect of linear elongation on carbon nanotube and polyelectrolyte structures in pdms-supported nanocomposite LbL films",
abstract = "Polyelectrolyte (PE) multilayer (PEM) thin films prepared by layer-by-layer self-assembly on flexible substrates are exposed to elongation in many fields of technology. Upon elongation, these types of films are showing interesting, but not understood, phenomena, such as controlled wetting, stimuliresponsive nanovalves, and lithography-free surface structuring. To investigate the mechanisms causing these interesting phenomena, we employed spectroscopic investigations of supported PEM films that were prepared from polystyrene sulfonate (PSS)-wrapped single-walled carbon nanotubes (SWNTs) or pyrene-labeled PSS (PSS-PY) and polydiallyldiammonium chloride. Our results show that the SWNTs agglomerated upon deposition into the PEM and showed a strong change in orientation upon uniaxial elongation of the PEM. Upon release of elongation, the resulting wrinkling pattern was changing its wavelength upon time, in the case of the SWNT-containing PEM. Fluorescence measurements of the PSS-PY in the PEM showed that the PEs changed their orientation due to constant mechanical force from elongation up to a time scale of 2 days after beginning the elongation. The results prove that elongated and released PEM films, until now considered static structures, possess strong kinetics, which has to be taken into account for their application.",
author = "Johannes Frueh and Naotoshi Nakashima and Qiang He and Helmuth M{\"o}hwald",
year = "2012",
month = "10",
day = "11",
doi = "10.1021/jp3071458",
language = "English",
volume = "116",
pages = "12257--12262",
journal = "Journal of Physical Chemistry B",
issn = "1520-6106",
number = "40",

}

TY - JOUR

T1 - Effect of linear elongation on carbon nanotube and polyelectrolyte structures in pdms-supported nanocomposite LbL films

AU - Frueh, Johannes

AU - Nakashima, Naotoshi

AU - He, Qiang

AU - Möhwald, Helmuth

PY - 2012/10/11

Y1 - 2012/10/11

N2 - Polyelectrolyte (PE) multilayer (PEM) thin films prepared by layer-by-layer self-assembly on flexible substrates are exposed to elongation in many fields of technology. Upon elongation, these types of films are showing interesting, but not understood, phenomena, such as controlled wetting, stimuliresponsive nanovalves, and lithography-free surface structuring. To investigate the mechanisms causing these interesting phenomena, we employed spectroscopic investigations of supported PEM films that were prepared from polystyrene sulfonate (PSS)-wrapped single-walled carbon nanotubes (SWNTs) or pyrene-labeled PSS (PSS-PY) and polydiallyldiammonium chloride. Our results show that the SWNTs agglomerated upon deposition into the PEM and showed a strong change in orientation upon uniaxial elongation of the PEM. Upon release of elongation, the resulting wrinkling pattern was changing its wavelength upon time, in the case of the SWNT-containing PEM. Fluorescence measurements of the PSS-PY in the PEM showed that the PEs changed their orientation due to constant mechanical force from elongation up to a time scale of 2 days after beginning the elongation. The results prove that elongated and released PEM films, until now considered static structures, possess strong kinetics, which has to be taken into account for their application.

AB - Polyelectrolyte (PE) multilayer (PEM) thin films prepared by layer-by-layer self-assembly on flexible substrates are exposed to elongation in many fields of technology. Upon elongation, these types of films are showing interesting, but not understood, phenomena, such as controlled wetting, stimuliresponsive nanovalves, and lithography-free surface structuring. To investigate the mechanisms causing these interesting phenomena, we employed spectroscopic investigations of supported PEM films that were prepared from polystyrene sulfonate (PSS)-wrapped single-walled carbon nanotubes (SWNTs) or pyrene-labeled PSS (PSS-PY) and polydiallyldiammonium chloride. Our results show that the SWNTs agglomerated upon deposition into the PEM and showed a strong change in orientation upon uniaxial elongation of the PEM. Upon release of elongation, the resulting wrinkling pattern was changing its wavelength upon time, in the case of the SWNT-containing PEM. Fluorescence measurements of the PSS-PY in the PEM showed that the PEs changed their orientation due to constant mechanical force from elongation up to a time scale of 2 days after beginning the elongation. The results prove that elongated and released PEM films, until now considered static structures, possess strong kinetics, which has to be taken into account for their application.

UR - http://www.scopus.com/inward/record.url?scp=84868142046&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84868142046&partnerID=8YFLogxK

U2 - 10.1021/jp3071458

DO - 10.1021/jp3071458

M3 - Article

C2 - 22978605

AN - SCOPUS:84868142046

VL - 116

SP - 12257

EP - 12262

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

SN - 1520-6106

IS - 40

ER -