The correlation energies (CEs) of the He isoelectronic sequence Z=2-116 with a point nuclear charge model were investigated with the four component relativistic configuration interaction method. We obtained CEs with and without the virtual pair approximation which are close to the values from Pestka 's Hylleraas-type configuration interaction calculation. We also found that the uniform charge and point charge models for the nucleus differ substantially for Z≥100.
|Journal||Journal of Chemical Physics|
|Publication status||Published - 2010|
All Science Journal Classification (ASJC) codes
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry