Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides

Daisuke Noda, Yusuke Sunada, Takuji Hatakeyama, Masaharu Nakamura, Hideo Nagashima

Research output: Contribution to journal › Article

174 Citations (Scopus)

Abstract

A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr2 and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.

Original languageEnglish
Pages (from-to)6078-6079
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number17
DOIs
Publication statusPublished - May 6 2009

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Iron
Cross Reactions
phenyllithium

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides. / Noda, Daisuke; Sunada, Yusuke; Hatakeyama, Takuji; Nakamura, Masaharu; Nagashima, Hideo.

In: Journal of the American Chemical Society, Vol. 131, No. 17, 06.05.2009, p. 6078-6079.

Research output: Contribution to journal › Article

Noda, D, Sunada, Y, Hatakeyama, T, Nakamura, M & Nagashima, H 2009, 'Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides', Journal of the American Chemical Society, vol. 131, no. 17, pp. 6078-6079. https://doi.org/10.1021/ja901262g
Noda D, Sunada Y, Hatakeyama T, Nakamura M, Nagashima H. Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides. Journal of the American Chemical Society. 2009 May 6;131(17):6078-6079. https://doi.org/10.1021/ja901262g
Noda, Daisuke ; Sunada, Yusuke ; Hatakeyama, Takuji ; Nakamura, Masaharu ; Nagashima, Hideo. / Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides. In: Journal of the American Chemical Society. 2009 ; Vol. 131, No. 17. pp. 6078-6079.
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