Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides

Daisuke Noda; Yusuke Sunada; Takuji Hatakeyama; Masaharu Nakamura; Hideo Nagashima

doi:10.1021/ja901262g

Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides

Daisuke Noda, Yusuke Sunada, Takuji Hatakeyama, Masaharu Nakamura, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

194 Citations (Scopus)

Abstract

A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr₂ and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.

Original language	English
Pages (from-to)	6078-6079
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	17
DOIs	https://doi.org/10.1021/ja901262g
Publication status	Published - May 6 2009

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja901262g

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title = "Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides",

abstract = "A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr2 and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.",

author = "Daisuke Noda and Yusuke Sunada and Takuji Hatakeyama and Masaharu Nakamura and Hideo Nagashima",

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AU - Sunada, Yusuke

AU - Hatakeyama, Takuji

AU - Nakamura, Masaharu

AU - Nagashima, Hideo

PY - 2009/5/6

Y1 - 2009/5/6

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AB - A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr2 and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.

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Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides

Abstract

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