Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides

Daisuke Noda; Yusuke Sunada; Takuji Hatakeyama; Masaharu Nakamura; Hideo Nagashima

doi:10.1021/ja901262g

Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides

Daisuke Noda, Yusuke Sunada, Takuji Hatakeyama, Masaharu Nakamura, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

199 Citations (Scopus)

Abstract

A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr₂ and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.

Original language	English
Pages (from-to)	6078-6079
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	17
DOIs	https://doi.org/10.1021/ja901262g
Publication status	Published - May 6 2009

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja901262g

Cite this

@article{6ffe1fadabab452fbaf77ec7af909d6b,

title = "Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides",

abstract = "A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr2 and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.",

author = "Daisuke Noda and Yusuke Sunada and Takuji Hatakeyama and Masaharu Nakamura and Hideo Nagashima",

year = "2009",

month = may,

day = "6",

doi = "10.1021/ja901262g",

language = "English",

volume = "131",

pages = "6078--6079",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "17",

}

TY - JOUR

T1 - Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides

AU - Noda, Daisuke

AU - Sunada, Yusuke

AU - Hatakeyama, Takuji

AU - Nakamura, Masaharu

AU - Nagashima, Hideo

PY - 2009/5/6

Y1 - 2009/5/6

N2 - A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr2 and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.

AB - A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr2 and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.

UR - http://www.scopus.com/inward/record.url?scp=69949165772&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=69949165772&partnerID=8YFLogxK

U2 - 10.1021/ja901262g

DO - 10.1021/ja901262g

M3 - Article

C2 - 19364096

AN - SCOPUS:69949165772

VL - 131

SP - 6078

EP - 6079

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 17

ER -

Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this