Effect of TMEDA on iron-catalyzed coupling reactions of ArMgX with alkyl halides

Daisuke Noda, Yusuke Sunada, Takuji Hatakeyama, Masaharu Nakamura, Hideo Nagashima

Research output: Contribution to journalArticlepeer-review

194 Citations (Scopus)

Abstract

A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr2 and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.

Original languageEnglish
Pages (from-to)6078-6079
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number17
DOIs
Publication statusPublished - May 6 2009

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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