Effects of a side chain aromatic ring on the reactivity of copper(I) complexes with dioxygen

Yuichi Shimazaki; Takeo Nogami; Fumito Tani; Akira Odani; Osamu Yamauchi

doi:10.1002/1521-3773(20011015)40:20<3859::AID-ANIE3859>3.0.CO;2-K

Effects of a side chain aromatic ring on the reactivity of copper(I) complexes with dioxygen

Yuichi Shimazaki, Takeo Nogami, Fumito Tani, Akira Odani, Osamu Yamauchi

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

Stabilization of the bis(μ-oxo)dicopper(III) intermediate is achieved by using a bidentate N-donor ligand with pendent indole rings: N,N-bis[(3-indolyl)methyl]N-[(2′-pyridyl)methyl]amine (BIP). The intermediate decomposes to give products arising from N-dealkylation and a product with a spiro ring composed of two indole rings (see scheme). This latter product probably results from a radical-coupling reaction.

Original language	English
Pages (from-to)	3859-3862
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	20
DOIs	https://doi.org/10.1002/1521-3773(20011015)40:20<3859::AID-ANIE3859>3.0.CO;2-K
Publication status	Published - Oct 15 2001

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1002/1521-3773(20011015)40:20<3859::AID-ANIE3859>3.0.CO;2-K

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abstract = "Stabilization of the bis(μ-oxo)dicopper(III) intermediate is achieved by using a bidentate N-donor ligand with pendent indole rings: N,N-bis[(3-indolyl)methyl]N-[(2′-pyridyl)methyl]amine (BIP). The intermediate decomposes to give products arising from N-dealkylation and a product with a spiro ring composed of two indole rings (see scheme). This latter product probably results from a radical-coupling reaction.",

author = "Yuichi Shimazaki and Takeo Nogami and Fumito Tani and Akira Odani and Osamu Yamauchi",

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T1 - Effects of a side chain aromatic ring on the reactivity of copper(I) complexes with dioxygen

AU - Shimazaki, Yuichi

AU - Nogami, Takeo

AU - Tani, Fumito

AU - Odani, Akira

AU - Yamauchi, Osamu

PY - 2001/10/15

Y1 - 2001/10/15

N2 - Stabilization of the bis(μ-oxo)dicopper(III) intermediate is achieved by using a bidentate N-donor ligand with pendent indole rings: N,N-bis[(3-indolyl)methyl]N-[(2′-pyridyl)methyl]amine (BIP). The intermediate decomposes to give products arising from N-dealkylation and a product with a spiro ring composed of two indole rings (see scheme). This latter product probably results from a radical-coupling reaction.

AB - Stabilization of the bis(μ-oxo)dicopper(III) intermediate is achieved by using a bidentate N-donor ligand with pendent indole rings: N,N-bis[(3-indolyl)methyl]N-[(2′-pyridyl)methyl]amine (BIP). The intermediate decomposes to give products arising from N-dealkylation and a product with a spiro ring composed of two indole rings (see scheme). This latter product probably results from a radical-coupling reaction.

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Effects of a side chain aromatic ring on the reactivity of copper(I) complexes with dioxygen

Abstract

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