Effects of Pt and ionomer ratios on the structure of catalyst layer

A theoretical model for polymer electrolyte fuel cells

H. Ishikawa, Y. Sugawara, G. Inoue, M. Kawase

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The 3D structure of the catalyst layer (CL) in the polymer electrolyte fuel cell (PEFC) is modeled with a Pt/carbon (Pt/C) ratio of 0.4–2.3 and ionomer/carbon (i/C) ratio of 0.5–1.5, and the structural properties are evaluated by numerical simulation. The models are constructed by mimicking the actual shapes of Pt particles and carbon aggregates, as well as the ionomer adhesion in real CLs. CLs with different compositions are characterized by structural properties such as Pt inter-particle distance, ionomer coating thickness, pore size distribution, tortuosity, and ionomer coverage on Pt. The results for Pt/C = 1.0, i/C = 1.0 with Pt loading of 0.3 mg cm−2 and 50% porosity are validated against measured data for CLs with the same composition. With increasing i/C ratio, the smaller pores disappear and the number of isolated pores increases; while the ionomer connection and its coverage on Pt are significantly enhanced at i/C ∼1.0. With increasing Pt/C ratio, the Pt inter-particle distance decreases as the particles connect with each other. The tortuosity of the pores and the ionomer exhibits a trade-off relation depending on the ionomer volume. Further CL design concepts to optimize both O2 diffusion and H+ conduction are discussed.

Original languageEnglish
Pages (from-to)196-204
Number of pages9
JournalJournal of Power Sources
Volume374
DOIs
Publication statusPublished - Jan 15 2018

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Ionomers
Electrolytes
fuel cells
Fuel cells
Polymers
electrolytes
catalysts
Carbon
Catalysts
carbon
polymers
porosity
Structural properties
adhesion
Chemical analysis
Pore size
coatings
conduction
Adhesion
Porosity

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

Cite this

Effects of Pt and ionomer ratios on the structure of catalyst layer : A theoretical model for polymer electrolyte fuel cells. / Ishikawa, H.; Sugawara, Y.; Inoue, G.; Kawase, M.

In: Journal of Power Sources, Vol. 374, 15.01.2018, p. 196-204.

Research output: Contribution to journalArticle

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