Efficient Electrogenerated Chemiluminescence of Pyrrolopyrrole Aza-BODIPYs in the Near-Infrared Region with Tripropylamine: Involving Formation of S2 and T2 States

Ryoichi Ishimatsu, Hirosato Shintaku, Yuto Kage, Misaki Kamioka, Soji Shimizu, Koji Nakano, Hiroyuki Furuta, Toshihiko Imato

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Abstract

Efficient electrogenerated chemiluminescences (ECLs) of three pyrrolopyrrole aza-BODIPYs in the near-infrared region by using tripropylamine as a coreactant are reported. Kinetic analysis based on Marcus theory indicates the direct formation of S2 and T2 states through the electron transfer reaction, which affects the ECL efficiencies.

Original languageEnglish
Pages (from-to)11791-11795
Number of pages5
JournalJournal of the American Chemical Society
Volume141
Issue number30
DOIs
Publication statusPublished - Jul 31 2019

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Chemiluminescence
Luminescence
Infrared radiation
Electrons
Kinetics
4,4-difluoro-4-bora-3a,4a-diaza-s-indacene
tripropylamine

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

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title = "Efficient Electrogenerated Chemiluminescence of Pyrrolopyrrole Aza-BODIPYs in the Near-Infrared Region with Tripropylamine: Involving Formation of S2 and T2 States",
abstract = "Efficient electrogenerated chemiluminescences (ECLs) of three pyrrolopyrrole aza-BODIPYs in the near-infrared region by using tripropylamine as a coreactant are reported. Kinetic analysis based on Marcus theory indicates the direct formation of S2 and T2 states through the electron transfer reaction, which affects the ECL efficiencies.",
author = "Ryoichi Ishimatsu and Hirosato Shintaku and Yuto Kage and Misaki Kamioka and Soji Shimizu and Koji Nakano and Hiroyuki Furuta and Toshihiko Imato",
year = "2019",
month = "7",
day = "31",
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language = "English",
volume = "141",
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journal = "Journal of the American Chemical Society",
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publisher = "American Chemical Society",
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TY - JOUR

T1 - Efficient Electrogenerated Chemiluminescence of Pyrrolopyrrole Aza-BODIPYs in the Near-Infrared Region with Tripropylamine

T2 - Involving Formation of S2 and T2 States

AU - Ishimatsu, Ryoichi

AU - Shintaku, Hirosato

AU - Kage, Yuto

AU - Kamioka, Misaki

AU - Shimizu, Soji

AU - Nakano, Koji

AU - Furuta, Hiroyuki

AU - Imato, Toshihiko

PY - 2019/7/31

Y1 - 2019/7/31

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AB - Efficient electrogenerated chemiluminescences (ECLs) of three pyrrolopyrrole aza-BODIPYs in the near-infrared region by using tripropylamine as a coreactant are reported. Kinetic analysis based on Marcus theory indicates the direct formation of S2 and T2 states through the electron transfer reaction, which affects the ECL efficiencies.

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DO - 10.1021/jacs.9b05245

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