Efficient levoglucosenone production by catalytic pyrolysis of cellulose mixed with ionic liquid

Shinji Kudo, Zhenwei Zhou, Koyo Norinaga, Jun Ichiro Hayashi

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44 Citations (Scopus)

Abstract

Levoglucosenone is a synthetically valuable and versatile compound that is present as a minor product of cellulose pyrolysis. Here, we report the catalytic pyrolysis of cellulose by mixing with 1-butyl-2,3-dimethylimidazolium triflate ionic liquid (IL), forming levoglucosenone in high yield. The catalysis of the IL was selectively directed to form levoglucosenone, while the low content of IL (50%) effectively prevented formation of char, leading to a yield near 20% even at 250 °C. The thermally stable IL could be fully recovered from the mixture pyrolyzed up to 300 °C and reutilized for pyrolysis.

Original languageEnglish
Pages (from-to)3306-3311
Number of pages6
JournalGreen Chemistry
Volume13
Issue number11
DOIs
Publication statusPublished - Nov 2011

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All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Pollution

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