Efficient utilization of nanospace of layered transition metal oxide HNbMoO6 as a strong, water-tolerant solid acid catalyst

Caio Tagusagawa; Atsushi Takagaki; Shigenobu Hayashi; Kazunari Domen

doi:10.1021/ja802478d

Efficient utilization of nanospace of layered transition metal oxide HNbMoO6 as a strong, water-tolerant solid acid catalyst

Caio Tagusagawa, Atsushi Takagaki, Shigenobu Hayashi, Kazunari Domen

Research output: Contribution to journal › Article › peer-review

101 Citations (Scopus)

Abstract

Layered HNbMoO₆ was found to function as a strong solid acid catalyst, exceeding the activity of zeolites and ion-exchange resins for Friedel-Crafts alkylation. HNbMoO₆ also exhibited high catalytic activity for esterification of hydrocarboxylic acid and hydration. The catalytic performance of layered HNbMoO₆ is attributed to the intercalation of reactants into the interlayer and the development of strong acidity.

Original language	English
Pages (from-to)	7230-7231
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	23
DOIs	https://doi.org/10.1021/ja802478d
Publication status	Published - Jun 11 2008
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

Access to Document

10.1021/ja802478d

Cite this

@article{c975c3527f1c4e679c237c5a94fcac9a,

title = "Efficient utilization of nanospace of layered transition metal oxide HNbMoO6 as a strong, water-tolerant solid acid catalyst",

abstract = "Layered HNbMoO6 was found to function as a strong solid acid catalyst, exceeding the activity of zeolites and ion-exchange resins for Friedel-Crafts alkylation. HNbMoO6 also exhibited high catalytic activity for esterification of hydrocarboxylic acid and hydration. The catalytic performance of layered HNbMoO6 is attributed to the intercalation of reactants into the interlayer and the development of strong acidity.",

author = "Caio Tagusagawa and Atsushi Takagaki and Shigenobu Hayashi and Kazunari Domen",

year = "2008",

month = jun,

day = "11",

doi = "10.1021/ja802478d",

language = "English",

volume = "130",

pages = "7230--7231",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "23",

}

TY - JOUR

T1 - Efficient utilization of nanospace of layered transition metal oxide HNbMoO6 as a strong, water-tolerant solid acid catalyst

AU - Tagusagawa, Caio

AU - Takagaki, Atsushi

AU - Hayashi, Shigenobu

AU - Domen, Kazunari

PY - 2008/6/11

Y1 - 2008/6/11

N2 - Layered HNbMoO6 was found to function as a strong solid acid catalyst, exceeding the activity of zeolites and ion-exchange resins for Friedel-Crafts alkylation. HNbMoO6 also exhibited high catalytic activity for esterification of hydrocarboxylic acid and hydration. The catalytic performance of layered HNbMoO6 is attributed to the intercalation of reactants into the interlayer and the development of strong acidity.

AB - Layered HNbMoO6 was found to function as a strong solid acid catalyst, exceeding the activity of zeolites and ion-exchange resins for Friedel-Crafts alkylation. HNbMoO6 also exhibited high catalytic activity for esterification of hydrocarboxylic acid and hydration. The catalytic performance of layered HNbMoO6 is attributed to the intercalation of reactants into the interlayer and the development of strong acidity.

UR - http://www.scopus.com/inward/record.url?scp=44949257331&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=44949257331&partnerID=8YFLogxK

U2 - 10.1021/ja802478d

DO - 10.1021/ja802478d

M3 - Article

C2 - 18473467

AN - SCOPUS:44949257331

VL - 130

SP - 7230

EP - 7231

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 23

ER -

Efficient utilization of nanospace of layered transition metal oxide HNbMoO6 as a strong, water-tolerant solid acid catalyst

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this