Efficient utilization of nanospace of layered transition metal oxide HNbMoO6 as a strong, water-tolerant solid acid catalyst

Caio Tagusagawa; Atsushi Takagaki; Shigenobu Hayashi; Kazunari Domen

doi:10.1021/ja802478d

Efficient utilization of nanospace of layered transition metal oxide HNbMoO6 as a strong, water-tolerant solid acid catalyst

Caio Tagusagawa, Atsushi Takagaki, Shigenobu Hayashi, Kazunari Domen

Research output: Contribution to journal › Article › peer-review

97 Citations (Scopus)

Abstract

Layered HNbMoO₆ was found to function as a strong solid acid catalyst, exceeding the activity of zeolites and ion-exchange resins for Friedel-Crafts alkylation. HNbMoO₆ also exhibited high catalytic activity for esterification of hydrocarboxylic acid and hydration. The catalytic performance of layered HNbMoO₆ is attributed to the intercalation of reactants into the interlayer and the development of strong acidity.

Original language	English
Pages (from-to)	7230-7231
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	23
DOIs	https://doi.org/10.1021/ja802478d
Publication status	Published - Jun 11 2008
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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abstract = "Layered HNbMoO6 was found to function as a strong solid acid catalyst, exceeding the activity of zeolites and ion-exchange resins for Friedel-Crafts alkylation. HNbMoO6 also exhibited high catalytic activity for esterification of hydrocarboxylic acid and hydration. The catalytic performance of layered HNbMoO6 is attributed to the intercalation of reactants into the interlayer and the development of strong acidity.",

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AU - Takagaki, Atsushi

AU - Hayashi, Shigenobu

AU - Domen, Kazunari

PY - 2008/6/11

Y1 - 2008/6/11

N2 - Layered HNbMoO6 was found to function as a strong solid acid catalyst, exceeding the activity of zeolites and ion-exchange resins for Friedel-Crafts alkylation. HNbMoO6 also exhibited high catalytic activity for esterification of hydrocarboxylic acid and hydration. The catalytic performance of layered HNbMoO6 is attributed to the intercalation of reactants into the interlayer and the development of strong acidity.

AB - Layered HNbMoO6 was found to function as a strong solid acid catalyst, exceeding the activity of zeolites and ion-exchange resins for Friedel-Crafts alkylation. HNbMoO6 also exhibited high catalytic activity for esterification of hydrocarboxylic acid and hydration. The catalytic performance of layered HNbMoO6 is attributed to the intercalation of reactants into the interlayer and the development of strong acidity.

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