Electric field-induced assembly of monodisperse polyhedral metal-organic framework crystals

Nobuhiro Yanai, Melinda Sindoro, Jing Yan, Steve Granick

    Research output: Contribution to journalArticlepeer-review

    107 Citations (Scopus)

    Abstract

    Monodisperse polyhedral metal-organic framework (MOF) particles up to 5 μm in size, large enough to enable in situ optical imaging of particle orientation, were synthesized by the strategy of simultaneous addition of two capping ligands with different binding strength during crystallization. Upon dispersing them in ethylene glycol and applying AC electric field, the particles facets link to form linear chains. We observe well-regulated crystal orientation not only for rhombic dodecahedra all of whose facets are equivalent, but also for truncated cubes with nondegenerate facets. After removing the electric field, chains disassemble if their facets contain even modest curvature, but remain intact if their facets are planar. This assembly strategy offers a general route to fabricate oriented polyhedral crystal arrays of potential interest for new applications and functions.

    Original languageEnglish
    Pages (from-to)34-37
    Number of pages4
    JournalJournal of the American Chemical Society
    Volume135
    Issue number1
    DOIs
    Publication statusPublished - Jan 9 2013

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Chemistry(all)
    • Biochemistry
    • Colloid and Surface Chemistry

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