Electro-functional octupolar π-conjugated columnar liquid crystals

Takuma Yasuda, Tomohiro Shimizu, Feng Liu, Goran Ungar, Takashi Kato

Research output: Contribution to journalArticle

116 Citations (Scopus)

Abstract

A series of propeller-shaped π-conjugated molecules based on 2,4,6-tris(thiophene-2-yl)-1,3,5-triazines has been designed and synthesized to obtain ambipolar charge-transporting liquid-crystalline materials. The 3-fold electron-donating aromatic units are attached to the electron-accepting triazine core, which forms electro-functional octupolar π-conjugated structures. These octupolar molecules self-organize into one-dimensional columnar nanostructures and exhibit ambipolar carrier transport behavior, which has been revealed by time-of-flight measurements. In this approach, electron-donor and acceptor electro-active segments are assembled individually in each column to give one-dimensional nanostructured materials with precisely tuned electronic properties. Their desirable electronic structures responsible for both hole and electron conductions have also been examined by cyclic voltammetry and theoretical calculations. The present results provide a new guideline and versatile approach to the design of ambipolar conductive nanostructured liquid-crystalline materials.

Original languageEnglish
Pages (from-to)13437-13444
Number of pages8
JournalJournal of the American Chemical Society
Volume133
Issue number34
DOIs
Publication statusPublished - Aug 31 2011
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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