Electrocatalytic hydrogenation of o-xylene in a PEM reactor as a study of a model reaction for hydrogen storage

Ken Takano, Hiroyuki Tateno, Yoshimasa Matsumura, Atsushi Fukazawa, Tsuneo Kashiwagi, Koji Nakabayashi, Kensaku Nagasawa, Shigenori Mitsushima, Mahito Atobe

Research output: Contribution to journalArticle

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Abstract

The electrocatalytic hydrogenation of o-xylene in a proton-exchange membrane (PEM) reactor with various cathode catalysts was carried out as a study of a model reaction for hydrogen storage. o-Xylene introduced in a PEM reactor underwent electrocatalytic hydrogenation to provide cis-1,2-dimethylcyclohexane as the main stereoisomer with moderate to good current efficiencies. The reaction proceeded in accordance with the Langmuir-Hinshelwood mechanism.

Original languageEnglish
Pages (from-to)1437-1439
Number of pages3
JournalChemistry Letters
Volume45
Issue number12
DOIs
Publication statusPublished - Jan 1 2016

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Hydrogen storage
Hydrogenation
Protons
Ion exchange
Membranes
Stereoisomerism
Cathodes
Catalysts
2-xylene
1,2-dimethylcyclohexane

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Electrocatalytic hydrogenation of o-xylene in a PEM reactor as a study of a model reaction for hydrogen storage. / Takano, Ken; Tateno, Hiroyuki; Matsumura, Yoshimasa; Fukazawa, Atsushi; Kashiwagi, Tsuneo; Nakabayashi, Koji; Nagasawa, Kensaku; Mitsushima, Shigenori; Atobe, Mahito.

In: Chemistry Letters, Vol. 45, No. 12, 01.01.2016, p. 1437-1439.

Research output: Contribution to journalArticle

Takano, K, Tateno, H, Matsumura, Y, Fukazawa, A, Kashiwagi, T, Nakabayashi, K, Nagasawa, K, Mitsushima, S & Atobe, M 2016, 'Electrocatalytic hydrogenation of o-xylene in a PEM reactor as a study of a model reaction for hydrogen storage', Chemistry Letters, vol. 45, no. 12, pp. 1437-1439. https://doi.org/10.1246/cl.160766
Takano, Ken ; Tateno, Hiroyuki ; Matsumura, Yoshimasa ; Fukazawa, Atsushi ; Kashiwagi, Tsuneo ; Nakabayashi, Koji ; Nagasawa, Kensaku ; Mitsushima, Shigenori ; Atobe, Mahito. / Electrocatalytic hydrogenation of o-xylene in a PEM reactor as a study of a model reaction for hydrogen storage. In: Chemistry Letters. 2016 ; Vol. 45, No. 12. pp. 1437-1439.
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