Electrochemical and thermal properties of P2-type Na2/3Fe 1/3Mn2/3O2 for Na-ion batteries

Jie Zhao, Jing Xu, Dae Hoe Lee, Nikolay Dimov, Ying Shirley Meng, Shigeto Okada

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

P2-type Na2/3Fe1/3Mn2/3O2 was prepared by means of solid-state reaction. Its electrochemical properties as a cathode for sodium-ion batteries were investigated in the 1.5-4.3 V range vs. Na metal. This material delivers an initial discharge capacity as high as 193 mAh/g and maintains 153 mAh/g in 40 cycles. Such a high reversible capacity is achieved because both Mn3+/Mn4+ and Fe3+/ Fe4+ become active in the studied voltage range, as confirmed by X-ray absorption spectroscopy (XAS). The thermal stability of charged cathodes was investigated by differential scanning calorimetry (DSC). Although the total heat generated by the fully charged Na0.25Fe1/3Mn 2/3O2 is larger than that of the Li0.5CoO 2 used as a reference, it is remarkably stable up to ca. 320 °C.

Original languageEnglish
Pages (from-to)235-239
Number of pages5
JournalJournal of Power Sources
Volume264
DOIs
Publication statusPublished - Oct 15 2014

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Electrochemical properties
electric batteries
Cathodes
Thermodynamic properties
thermodynamic properties
cathodes
Ions
X ray absorption spectroscopy
Solid state reactions
Differential scanning calorimetry
Enthalpy
absorption spectroscopy
ions
Thermodynamic stability
thermal stability
heat measurement
Metals
Sodium
sodium
solid state

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

Cite this

Electrochemical and thermal properties of P2-type Na2/3Fe 1/3Mn2/3O2 for Na-ion batteries. / Zhao, Jie; Xu, Jing; Lee, Dae Hoe; Dimov, Nikolay; Meng, Ying Shirley; Okada, Shigeto.

In: Journal of Power Sources, Vol. 264, 15.10.2014, p. 235-239.

Research output: Contribution to journalArticle

Zhao, Jie ; Xu, Jing ; Lee, Dae Hoe ; Dimov, Nikolay ; Meng, Ying Shirley ; Okada, Shigeto. / Electrochemical and thermal properties of P2-type Na2/3Fe 1/3Mn2/3O2 for Na-ion batteries. In: Journal of Power Sources. 2014 ; Vol. 264. pp. 235-239.
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