Electrochemical approach to trifluoroacetamide synthesis from 1,1,1-trichloro-2,2,2-trifluoroethane (CFC-113a) catalyzed by B12complex

Mohammad Moniruzzaman, Yoshio Yano, Toshikazu Ono, Yoshio Hisaeda, Hisashi Shimakoshi

Research output: Contribution to journalArticlepeer-review

Abstract

One-pot synthetic approach to produce trifluoroacetamide has been developed using an electrochemical method with the B12 complex as a catalyst under mild conditions, in open air at room temperature. Thirty examples of trifluoroacetamide were synthesized from 1,1,1-trichloro-2,2,2-trifluoroethane (CFC-113a) in moderate to good yields. This user-friendly strategy is compatible with a broad range of trifluoroacetamide syntheses.

Original languageEnglish
JournalJournal of Porphyrins and Phthalocyanines
DOIs
Publication statusAccepted/In press - 2021

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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