Electrochemical hydrogen isotope sensing via the high-temperature proton conductor CaZr0.90In0.10O3-α

Hiroshige Matsumoto; Hiroyuki Hayashi; Tetsuo Shimura; Hiroyasu Iwahara; Toshinobu Yogo

doi:10.1016/S0167-2738(03)00212-1

Electrochemical hydrogen isotope sensing via the high-temperature proton conductor CaZr_0.90In_0.10O_3-α

Hiroshige Matsumoto, Hiroyuki Hayashi, Tetsuo Shimura, Hiroyasu Iwahara, Toshinobu Yogo

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The electromotive force (EMF) behavior of the hydrogen isotope cell using high-temperature proton conductors has been investigated. In the present study, the EMFs for H₂-D₂ mixtures and those for H ₂-D₂ mixtures diluted with argon against the H ₂ and D₂ reference gases were measured for an electrochemical cell using a proton-conducting electrolyte of CaZr _0.90In_0.10O_3-α. The theoretical equation for the hydrogen isotope cell was derived and compared to the measured EMFs to confirm its validity. The EMF of the cell can determine the atomic molar fraction of the hydrogen isotopes for gases in which the total pressures of the hydrogen isotopes are known.

Original language	English
Pages (from-to)	93-103
Number of pages	11
Journal	Solid State Ionics
Volume	161
Issue number	1-2
DOIs	https://doi.org/10.1016/S0167-2738(03)00212-1
Publication status	Published - Jul 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1016/S0167-2738(03)00212-1

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@article{fe793b42d1dd4902be7d593dbba870d3,

title = "Electrochemical hydrogen isotope sensing via the high-temperature proton conductor CaZr0.90In0.10O3-α",

abstract = "The electromotive force (EMF) behavior of the hydrogen isotope cell using high-temperature proton conductors has been investigated. In the present study, the EMFs for H2-D2 mixtures and those for H 2-D2 mixtures diluted with argon against the H 2 and D2 reference gases were measured for an electrochemical cell using a proton-conducting electrolyte of CaZr 0.90In0.10O3-α. The theoretical equation for the hydrogen isotope cell was derived and compared to the measured EMFs to confirm its validity. The EMF of the cell can determine the atomic molar fraction of the hydrogen isotopes for gases in which the total pressures of the hydrogen isotopes are known.",

author = "Hiroshige Matsumoto and Hiroyuki Hayashi and Tetsuo Shimura and Hiroyasu Iwahara and Toshinobu Yogo",

note = "Funding Information: This study was supported in part by a Grant-in-Aid for Science and Research from the Ministry of Education, Science, Sports and Culture, Japan. Dr. T. Kawada and Mr. K. Yashiro are acknowledged for their help in revising the manuscript. ",

year = "2003",

month = jul,

doi = "10.1016/S0167-2738(03)00212-1",

language = "English",

volume = "161",

pages = "93--103",

journal = "Solid State Ionics",

issn = "0167-2738",

publisher = "Elsevier",

number = "1-2",

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TY - JOUR

T1 - Electrochemical hydrogen isotope sensing via the high-temperature proton conductor CaZr0.90In0.10O3-α

AU - Matsumoto, Hiroshige

AU - Hayashi, Hiroyuki

AU - Shimura, Tetsuo

AU - Iwahara, Hiroyasu

AU - Yogo, Toshinobu

N1 - Funding Information: This study was supported in part by a Grant-in-Aid for Science and Research from the Ministry of Education, Science, Sports and Culture, Japan. Dr. T. Kawada and Mr. K. Yashiro are acknowledged for their help in revising the manuscript.

PY - 2003/7

Y1 - 2003/7

N2 - The electromotive force (EMF) behavior of the hydrogen isotope cell using high-temperature proton conductors has been investigated. In the present study, the EMFs for H2-D2 mixtures and those for H 2-D2 mixtures diluted with argon against the H 2 and D2 reference gases were measured for an electrochemical cell using a proton-conducting electrolyte of CaZr 0.90In0.10O3-α. The theoretical equation for the hydrogen isotope cell was derived and compared to the measured EMFs to confirm its validity. The EMF of the cell can determine the atomic molar fraction of the hydrogen isotopes for gases in which the total pressures of the hydrogen isotopes are known.

AB - The electromotive force (EMF) behavior of the hydrogen isotope cell using high-temperature proton conductors has been investigated. In the present study, the EMFs for H2-D2 mixtures and those for H 2-D2 mixtures diluted with argon against the H 2 and D2 reference gases were measured for an electrochemical cell using a proton-conducting electrolyte of CaZr 0.90In0.10O3-α. The theoretical equation for the hydrogen isotope cell was derived and compared to the measured EMFs to confirm its validity. The EMF of the cell can determine the atomic molar fraction of the hydrogen isotopes for gases in which the total pressures of the hydrogen isotopes are known.

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