Electrochemical oxidation of 1,3,5-tris(diphenylamino)benzene (TDAB) for polyradical material

Kazunari Yoshizawa, Akihiro Ito, Kazuyoshi Tanaka, Tokio Yamabe

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Abstract

Electrochemical coupling of 1,3,5-tris(diphenylamino)benzene (TDAB) occurs in dichloromethane or trichloroethane solution in the presence of tetrabutylammonium tetrafluoroborate or perchlorate. The obtained material contains radical cations, the spin concentration of which is of the order 1019 g-1. An anodic reaction pathway of TDAB is proposed on the basis of the dimerization mechanism of the triphenylaminium radical cation.

Original languageEnglish
Pages (from-to)81-83
Number of pages3
JournalSynthetic Metals
Volume66
Issue number1
DOIs
Publication statusPublished - Sep 15 1994
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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