Electrochemical oxidation of 1,3,5-tris(diphenylamino)benzene (TDAB) for polyradical material

Kazunari Yoshizawa; Akihiro Ito; Kazuyoshi Tanaka; Tokio Yamabe

doi:10.1016/0379-6779(94)90165-1

Electrochemical oxidation of 1,3,5-tris(diphenylamino)benzene (TDAB) for polyradical material

Kazunari Yoshizawa, Akihiro Ito, Kazuyoshi Tanaka, Tokio Yamabe

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Electrochemical coupling of 1,3,5-tris(diphenylamino)benzene (TDAB) occurs in dichloromethane or trichloroethane solution in the presence of tetrabutylammonium tetrafluoroborate or perchlorate. The obtained material contains radical cations, the spin concentration of which is of the order 10¹⁹ g^-1. An anodic reaction pathway of TDAB is proposed on the basis of the dimerization mechanism of the triphenylaminium radical cation.

Original language	English
Pages (from-to)	81-83
Number of pages	3
Journal	Synthetic Metals
Volume	66
Issue number	1
DOIs	https://doi.org/10.1016/0379-6779(94)90165-1
Publication status	Published - Sept 15 1994
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/0379-6779(94)90165-1

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abstract = "Electrochemical coupling of 1,3,5-tris(diphenylamino)benzene (TDAB) occurs in dichloromethane or trichloroethane solution in the presence of tetrabutylammonium tetrafluoroborate or perchlorate. The obtained material contains radical cations, the spin concentration of which is of the order 1019 g-1. An anodic reaction pathway of TDAB is proposed on the basis of the dimerization mechanism of the triphenylaminium radical cation.",

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AU - Yoshizawa, Kazunari

AU - Ito, Akihiro

AU - Tanaka, Kazuyoshi

AU - Yamabe, Tokio

PY - 1994/9/15

Y1 - 1994/9/15

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AB - Electrochemical coupling of 1,3,5-tris(diphenylamino)benzene (TDAB) occurs in dichloromethane or trichloroethane solution in the presence of tetrabutylammonium tetrafluoroborate or perchlorate. The obtained material contains radical cations, the spin concentration of which is of the order 1019 g-1. An anodic reaction pathway of TDAB is proposed on the basis of the dimerization mechanism of the triphenylaminium radical cation.

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Electrochemical oxidation of 1,3,5-tris(diphenylamino)benzene (TDAB) for polyradical material

Abstract

All Science Journal Classification (ASJC) codes

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