Electrochemical Properties of Self-Assembled Monolayers Composed of TTF Derivative

Ryota Yuge; Akira Miyazaki; Toshiaki Enoki; Kaoru Tamada; Fumio Nakamura; Masahiko Hara

doi:10.1080/713738564

Electrochemical Properties of Self-Assembled Monolayers Composed of TTF Derivative

Ryota Yuge, Akira Miyazaki, Toshiaki Enoki, Kaoru Tamada, Fumio Nakamura, Masahiko Hara

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We prepared self-assembled monolayers (SAMs) composed of tetrathiafulvalene (TTF) derivative modified on gold substrate and investigate their electrochemical properties by cyclic voltammogram (CV). The first and second oxidation peaks were observed at E 1 1/2 =0.40 V and E 2 1/2 =0.81 V, respectively. The peak current was observed to be proportional to the scan rate, suggesting the feature of modified SAMs molecules. The result indicates that TTF-thiolate SAMs on gold electrode have electronic structure similar to bulk TTF molecules.

Original language	English
Pages (from-to)	395-398
Number of pages	4
Journal	Molecular Crystals and Liquid Crystals
Volume	377
Issue number	1
DOIs	https://doi.org/10.1080/713738564
Publication status	Published - 2002

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Electrochemical Properties of Self-Assembled Monolayers Composed of TTF Derivative",

abstract = "We prepared self-assembled monolayers (SAMs) composed of tetrathiafulvalene (TTF) derivative modified on gold substrate and investigate their electrochemical properties by cyclic voltammogram (CV). The first and second oxidation peaks were observed at E 1 1/2 =0.40 V and E 2 1/2 =0.81 V, respectively. The peak current was observed to be proportional to the scan rate, suggesting the feature of modified SAMs molecules. The result indicates that TTF-thiolate SAMs on gold electrode have electronic structure similar to bulk TTF molecules.",

author = "Ryota Yuge and Akira Miyazaki and Toshiaki Enoki and Kaoru Tamada and Fumio Nakamura and Masahiko Hara",

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T1 - Electrochemical Properties of Self-Assembled Monolayers Composed of TTF Derivative

AU - Yuge, Ryota

AU - Miyazaki, Akira

AU - Enoki, Toshiaki

AU - Tamada, Kaoru

AU - Nakamura, Fumio

AU - Hara, Masahiko

PY - 2002

Y1 - 2002

N2 - We prepared self-assembled monolayers (SAMs) composed of tetrathiafulvalene (TTF) derivative modified on gold substrate and investigate their electrochemical properties by cyclic voltammogram (CV). The first and second oxidation peaks were observed at E 1 1/2 =0.40 V and E 2 1/2 =0.81 V, respectively. The peak current was observed to be proportional to the scan rate, suggesting the feature of modified SAMs molecules. The result indicates that TTF-thiolate SAMs on gold electrode have electronic structure similar to bulk TTF molecules.

AB - We prepared self-assembled monolayers (SAMs) composed of tetrathiafulvalene (TTF) derivative modified on gold substrate and investigate their electrochemical properties by cyclic voltammogram (CV). The first and second oxidation peaks were observed at E 1 1/2 =0.40 V and E 2 1/2 =0.81 V, respectively. The peak current was observed to be proportional to the scan rate, suggesting the feature of modified SAMs molecules. The result indicates that TTF-thiolate SAMs on gold electrode have electronic structure similar to bulk TTF molecules.

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Electrochemical Properties of Self-Assembled Monolayers Composed of TTF Derivative

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