Electrochemical properties of tin oxide anodes for sodium-ion batteries

Ying Ching Lu; Chuze Ma; Judith Alvarado; Takafumi Kidera; Nikolay Dimov; Ying Shirley Meng; Shigeto Okada

doi:10.1016/j.jpowsour.2015.03.042

Electrochemical properties of tin oxide anodes for sodium-ion batteries

Ying Ching Lu, Chuze Ma, Judith Alvarado, Takafumi Kidera, Nikolay Dimov, Ying Shirley Meng, Shigeto Okada

Department of Advanced Device Materials

Research output: Contribution to journal › Article › peer-review

87 Citations (Scopus)

Abstract

Abstract Few tin (Sn)-oxide based anode materials have been found to have large reversible capacity for both sodium (Na)-ion and lithium (Li)-ion batteries. Herein, we report the synthesis and electrochemical properties of Sn oxide-based anodes for sodium-ion batteries: SnO, SnO₂, and SnO₂/C. Among them, SnO is the most suitable anode for Na-ion batteries with less first cycle irreversibility, better cycle life, and lower charge transfer resistance. The energy storage mechanism of the above-mentioned Sn oxides was studied, which suggested that the conversion reaction of the Sn oxide anodes is reversible in Na-ion batteries. The better anode performance of SnO is attributed by the better conductivity.

Original language	English
Article number	20831
Pages (from-to)	287-295
Number of pages	9
Journal	Journal of Power Sources
Volume	284
DOIs	https://doi.org/10.1016/j.jpowsour.2015.03.042
Publication status	Published - Jun 15 2015

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

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title = "Electrochemical properties of tin oxide anodes for sodium-ion batteries",

abstract = "Abstract Few tin (Sn)-oxide based anode materials have been found to have large reversible capacity for both sodium (Na)-ion and lithium (Li)-ion batteries. Herein, we report the synthesis and electrochemical properties of Sn oxide-based anodes for sodium-ion batteries: SnO, SnO2, and SnO2/C. Among them, SnO is the most suitable anode for Na-ion batteries with less first cycle irreversibility, better cycle life, and lower charge transfer resistance. The energy storage mechanism of the above-mentioned Sn oxides was studied, which suggested that the conversion reaction of the Sn oxide anodes is reversible in Na-ion batteries. The better anode performance of SnO is attributed by the better conductivity.",

author = "Lu, {Ying Ching} and Chuze Ma and Judith Alvarado and Takafumi Kidera and Nikolay Dimov and Meng, {Ying Shirley} and Shigeto Okada",

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T1 - Electrochemical properties of tin oxide anodes for sodium-ion batteries

AU - Lu, Ying Ching

AU - Ma, Chuze

AU - Alvarado, Judith

AU - Kidera, Takafumi

AU - Dimov, Nikolay

AU - Meng, Ying Shirley

AU - Okada, Shigeto

PY - 2015/6/15

Y1 - 2015/6/15

N2 - Abstract Few tin (Sn)-oxide based anode materials have been found to have large reversible capacity for both sodium (Na)-ion and lithium (Li)-ion batteries. Herein, we report the synthesis and electrochemical properties of Sn oxide-based anodes for sodium-ion batteries: SnO, SnO2, and SnO2/C. Among them, SnO is the most suitable anode for Na-ion batteries with less first cycle irreversibility, better cycle life, and lower charge transfer resistance. The energy storage mechanism of the above-mentioned Sn oxides was studied, which suggested that the conversion reaction of the Sn oxide anodes is reversible in Na-ion batteries. The better anode performance of SnO is attributed by the better conductivity.

AB - Abstract Few tin (Sn)-oxide based anode materials have been found to have large reversible capacity for both sodium (Na)-ion and lithium (Li)-ion batteries. Herein, we report the synthesis and electrochemical properties of Sn oxide-based anodes for sodium-ion batteries: SnO, SnO2, and SnO2/C. Among them, SnO is the most suitable anode for Na-ion batteries with less first cycle irreversibility, better cycle life, and lower charge transfer resistance. The energy storage mechanism of the above-mentioned Sn oxides was studied, which suggested that the conversion reaction of the Sn oxide anodes is reversible in Na-ion batteries. The better anode performance of SnO is attributed by the better conductivity.

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