Electrochemical properties of tin oxide anodes for sodium-ion batteries

Ying Ching Lu; Chuze Ma; Judith Alvarado; Takafumi Kidera; Nikolay Dimov; Ying Shirley Meng; Shigeto Okada

doi:10.1016/j.jpowsour.2015.03.042

Electrochemical properties of tin oxide anodes for sodium-ion batteries

Ying Ching Lu, Chuze Ma, Judith Alvarado, Takafumi Kidera, Nikolay Dimov, Ying Shirley Meng, Shigeto Okada

Advanced Device Materials

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77 Citations (Scopus)

Abstract

Abstract Few tin (Sn)-oxide based anode materials have been found to have large reversible capacity for both sodium (Na)-ion and lithium (Li)-ion batteries. Herein, we report the synthesis and electrochemical properties of Sn oxide-based anodes for sodium-ion batteries: SnO, SnO₂, and SnO₂/C. Among them, SnO is the most suitable anode for Na-ion batteries with less first cycle irreversibility, better cycle life, and lower charge transfer resistance. The energy storage mechanism of the above-mentioned Sn oxides was studied, which suggested that the conversion reaction of the Sn oxide anodes is reversible in Na-ion batteries. The better anode performance of SnO is attributed by the better conductivity.

Original language	English
Article number	20831
Pages (from-to)	287-295
Number of pages	9
Journal	Journal of Power Sources
Volume	284
DOIs	https://doi.org/10.1016/j.jpowsour.2015.03.042
Publication status	Published - Jun 15 2015

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All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

Cite this

Lu, Y. C., Ma, C., Alvarado, J., Kidera, T., Dimov, N., Meng, Y. S., & Okada, S. (2015). Electrochemical properties of tin oxide anodes for sodium-ion batteries. Journal of Power Sources, 284, 287-295. [20831]. https://doi.org/10.1016/j.jpowsour.2015.03.042

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abstract = "Abstract Few tin (Sn)-oxide based anode materials have been found to have large reversible capacity for both sodium (Na)-ion and lithium (Li)-ion batteries. Herein, we report the synthesis and electrochemical properties of Sn oxide-based anodes for sodium-ion batteries: SnO, SnO2, and SnO2/C. Among them, SnO is the most suitable anode for Na-ion batteries with less first cycle irreversibility, better cycle life, and lower charge transfer resistance. The energy storage mechanism of the above-mentioned Sn oxides was studied, which suggested that the conversion reaction of the Sn oxide anodes is reversible in Na-ion batteries. The better anode performance of SnO is attributed by the better conductivity.",

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AU - Lu, Ying Ching

AU - Ma, Chuze

AU - Alvarado, Judith

AU - Kidera, Takafumi

AU - Dimov, Nikolay

AU - Meng, Ying Shirley

AU - Okada, Shigeto

PY - 2015/6/15

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N2 - Abstract Few tin (Sn)-oxide based anode materials have been found to have large reversible capacity for both sodium (Na)-ion and lithium (Li)-ion batteries. Herein, we report the synthesis and electrochemical properties of Sn oxide-based anodes for sodium-ion batteries: SnO, SnO2, and SnO2/C. Among them, SnO is the most suitable anode for Na-ion batteries with less first cycle irreversibility, better cycle life, and lower charge transfer resistance. The energy storage mechanism of the above-mentioned Sn oxides was studied, which suggested that the conversion reaction of the Sn oxide anodes is reversible in Na-ion batteries. The better anode performance of SnO is attributed by the better conductivity.

AB - Abstract Few tin (Sn)-oxide based anode materials have been found to have large reversible capacity for both sodium (Na)-ion and lithium (Li)-ion batteries. Herein, we report the synthesis and electrochemical properties of Sn oxide-based anodes for sodium-ion batteries: SnO, SnO2, and SnO2/C. Among them, SnO is the most suitable anode for Na-ion batteries with less first cycle irreversibility, better cycle life, and lower charge transfer resistance. The energy storage mechanism of the above-mentioned Sn oxides was studied, which suggested that the conversion reaction of the Sn oxide anodes is reversible in Na-ion batteries. The better anode performance of SnO is attributed by the better conductivity.

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10.1016/j.jpowsour.2015.03.042