Electrochemical responses of a polyeugenol and overoxidized polypyrrole composite film modified graphite electrode to dopamine and ascorbic acid

Koji Hirakawa, Toshihiko Imato, Sumio Yamasaki, Hiroki Ohura

Research output: Contribution to conferencePaper

4 Citations (Scopus)

Abstract

The electrochemical response of a graphite electrode modified with a polyeugenol-overoxidized polypyrrole composite film to dopamine and ascorbic acid was investigated by a voltammetric, method. The modification of the electrode was carried out by electropolymerization of monomer of eugenol and subsequent electropolymerization of pyrrole in an alkaline solution by cyclic voltammetry. The composite film modified electrode exhibited an enhanced anodic current response to dopamine by about 10 times compared to the bare electrode, while its anodic current response to ascorbic acid was suppressed by ca. a half compared to the bare electrode. Dopamine could be determined with a linear response range of 0.5-10 μmol/1, and with the sensitivity of 5.5 μA/μM. The origin of high selectivity and sensitivity of the present electrode modified with the composite film was estimated to be due to the oxidization of the surface of the electrode and modification with the polyeugenol-overoxidized polypyrrole composite film with permselectivity to dopamine against ascorbic acid.

Original languageEnglish
Pages438-443
Number of pages6
Publication statusPublished - Dec 1 2004
EventChemical Sensors VI: Chemical and Biological Sensors and Analytical Methods - Proceedings of the International Symposium - Honolulu, HI, United States
Duration: Oct 3 2004Oct 8 2004

Other

OtherChemical Sensors VI: Chemical and Biological Sensors and Analytical Methods - Proceedings of the International Symposium
CountryUnited States
CityHonolulu, HI
Period10/3/0410/8/04

Fingerprint

Graphite electrodes
Ascorbic acid
Polypyrroles
Composite films
Electrodes
Electropolymerization
Cyclic voltammetry
Dopamine
Monomers

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Hirakawa, K., Imato, T., Yamasaki, S., & Ohura, H. (2004). Electrochemical responses of a polyeugenol and overoxidized polypyrrole composite film modified graphite electrode to dopamine and ascorbic acid. 438-443. Paper presented at Chemical Sensors VI: Chemical and Biological Sensors and Analytical Methods - Proceedings of the International Symposium, Honolulu, HI, United States.

Electrochemical responses of a polyeugenol and overoxidized polypyrrole composite film modified graphite electrode to dopamine and ascorbic acid. / Hirakawa, Koji; Imato, Toshihiko; Yamasaki, Sumio; Ohura, Hiroki.

2004. 438-443 Paper presented at Chemical Sensors VI: Chemical and Biological Sensors and Analytical Methods - Proceedings of the International Symposium, Honolulu, HI, United States.

Research output: Contribution to conferencePaper

Hirakawa, K, Imato, T, Yamasaki, S & Ohura, H 2004, 'Electrochemical responses of a polyeugenol and overoxidized polypyrrole composite film modified graphite electrode to dopamine and ascorbic acid', Paper presented at Chemical Sensors VI: Chemical and Biological Sensors and Analytical Methods - Proceedings of the International Symposium, Honolulu, HI, United States, 10/3/04 - 10/8/04 pp. 438-443.
Hirakawa K, Imato T, Yamasaki S, Ohura H. Electrochemical responses of a polyeugenol and overoxidized polypyrrole composite film modified graphite electrode to dopamine and ascorbic acid. 2004. Paper presented at Chemical Sensors VI: Chemical and Biological Sensors and Analytical Methods - Proceedings of the International Symposium, Honolulu, HI, United States.
Hirakawa, Koji ; Imato, Toshihiko ; Yamasaki, Sumio ; Ohura, Hiroki. / Electrochemical responses of a polyeugenol and overoxidized polypyrrole composite film modified graphite electrode to dopamine and ascorbic acid. Paper presented at Chemical Sensors VI: Chemical and Biological Sensors and Analytical Methods - Proceedings of the International Symposium, Honolulu, HI, United States.6 p.
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N2 - The electrochemical response of a graphite electrode modified with a polyeugenol-overoxidized polypyrrole composite film to dopamine and ascorbic acid was investigated by a voltammetric, method. The modification of the electrode was carried out by electropolymerization of monomer of eugenol and subsequent electropolymerization of pyrrole in an alkaline solution by cyclic voltammetry. The composite film modified electrode exhibited an enhanced anodic current response to dopamine by about 10 times compared to the bare electrode, while its anodic current response to ascorbic acid was suppressed by ca. a half compared to the bare electrode. Dopamine could be determined with a linear response range of 0.5-10 μmol/1, and with the sensitivity of 5.5 μA/μM. The origin of high selectivity and sensitivity of the present electrode modified with the composite film was estimated to be due to the oxidization of the surface of the electrode and modification with the polyeugenol-overoxidized polypyrrole composite film with permselectivity to dopamine against ascorbic acid.

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