Electrochromic thin films of organic-metallo hybrid polymers

Akari Hayashi, Masayoshi Higuchi, Yuhki Ohtsuka, Dirk G. Kruth

Research output: Contribution to conferencePaper

Abstract

Organic-metallo hybrid polymers attract considerable attention in terms of designing and fabricating materials since metals and ligands of polymer components can be easily changed. One of the goals to design the molecular materials is the development of reversible and efficient molecular switches for optical and electronic applications, and electrochromic materials and devices are of major subject. We are interested in tepyridine-metal hybrid polymers because terpyridine ligands posses an excellent ability to coordinate metal ions. Self-assembly of 1,4-bis(2,2':6',2"-terpyridin-4'-yl)benzene and Fe(II) or Co(II) results in metallosupuramolecular polyelectrolytes (MEPE). Thin films of both Fe(II)- and Co(II)-MEPE showed reversible oxidation to Fe(III) or Co(III), and reduction to Fe(II) or Co(II). Fe-MEPE showed high redox respond, followed by dramatic color change between blue and colorless clear. Here, electrochromic properties of those thin films are reported.

Original languageEnglish
Number of pages1
Publication statusPublished - Dec 1 2005
Externally publishedYes
Event54th SPSJ Symposium on Macromolecules - Yamagata, Japan
Duration: Sep 20 2005Sep 22 2005

Other

Other54th SPSJ Symposium on Macromolecules
CountryJapan
CityYamagata
Period9/20/059/22/05

Fingerprint

Polyelectrolytes
Thin films
Polymers
Ligands
Metals
Self assembly
Metal ions
Benzene
Switches
Color
Oxidation

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Hayashi, A., Higuchi, M., Ohtsuka, Y., & Kruth, D. G. (2005). Electrochromic thin films of organic-metallo hybrid polymers. Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan.

Electrochromic thin films of organic-metallo hybrid polymers. / Hayashi, Akari; Higuchi, Masayoshi; Ohtsuka, Yuhki; Kruth, Dirk G.

2005. Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan.

Research output: Contribution to conferencePaper

Hayashi, A, Higuchi, M, Ohtsuka, Y & Kruth, DG 2005, 'Electrochromic thin films of organic-metallo hybrid polymers', Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan, 9/20/05 - 9/22/05.
Hayashi A, Higuchi M, Ohtsuka Y, Kruth DG. Electrochromic thin films of organic-metallo hybrid polymers. 2005. Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan.
Hayashi, Akari ; Higuchi, Masayoshi ; Ohtsuka, Yuhki ; Kruth, Dirk G. / Electrochromic thin films of organic-metallo hybrid polymers. Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan.1 p.
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