Electromotive force of hydrogen isotope cell with a high temperature proton-conducting solid electrolyte CaZr0.90In0.10O3-α

H. Matsumoto; K. Takeuchi; H. Iwahara

doi:10.1149/1.1391791

Electromotive force of hydrogen isotope cell with a high temperature proton-conducting solid electrolyte CaZr_0.90In_0.10O_3-α

H. Matsumoto, K. Takeuchi, H. Iwahara

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The electromotive force (EMF) of hydrogen isotope cell with a proton-conducting solid electrolyte CaZr_0.90In_0.10O_3-α was investigated at 500 approx. 900°C. This kind of cell (H₂/D₂) gave steady and reproducible EMF for which the D₂ side electrode was positive. The EMF could be explained by the two factors, i.e., the difference in mobilities of proton and deuteron in the electrolyte and the electrode reactions of H₂ and D₂ gases. The EMF of the cell for mixed isotope gases was nearly linear with the composition of hydrogen isotopes with a slight deviation and was consistent with such a mechanism of EMF of hydrogen isotope cell.

Original language	English
Pages (from-to)	1486-1491
Number of pages	6
Journal	Journal of the Electrochemical Society
Volume	146
Issue number	4
DOIs	https://doi.org/10.1149/1.1391791
Publication status	Published - Apr 1999
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Surfaces, Coatings and Films
Electrochemistry
Materials Chemistry

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This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1149/1.1391791

Cite this

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title = "Electromotive force of hydrogen isotope cell with a high temperature proton-conducting solid electrolyte CaZr0.90In0.10O3-α",

abstract = "The electromotive force (EMF) of hydrogen isotope cell with a proton-conducting solid electrolyte CaZr0.90In0.10O3-α was investigated at 500 approx. 900°C. This kind of cell (H2/D2) gave steady and reproducible EMF for which the D2 side electrode was positive. The EMF could be explained by the two factors, i.e., the difference in mobilities of proton and deuteron in the electrolyte and the electrode reactions of H2 and D2 gases. The EMF of the cell for mixed isotope gases was nearly linear with the composition of hydrogen isotopes with a slight deviation and was consistent with such a mechanism of EMF of hydrogen isotope cell.",

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T1 - Electromotive force of hydrogen isotope cell with a high temperature proton-conducting solid electrolyte CaZr0.90In0.10O3-α

AU - Matsumoto, H.

AU - Takeuchi, K.

AU - Iwahara, H.

PY - 1999/4

Y1 - 1999/4

N2 - The electromotive force (EMF) of hydrogen isotope cell with a proton-conducting solid electrolyte CaZr0.90In0.10O3-α was investigated at 500 approx. 900°C. This kind of cell (H2/D2) gave steady and reproducible EMF for which the D2 side electrode was positive. The EMF could be explained by the two factors, i.e., the difference in mobilities of proton and deuteron in the electrolyte and the electrode reactions of H2 and D2 gases. The EMF of the cell for mixed isotope gases was nearly linear with the composition of hydrogen isotopes with a slight deviation and was consistent with such a mechanism of EMF of hydrogen isotope cell.

AB - The electromotive force (EMF) of hydrogen isotope cell with a proton-conducting solid electrolyte CaZr0.90In0.10O3-α was investigated at 500 approx. 900°C. This kind of cell (H2/D2) gave steady and reproducible EMF for which the D2 side electrode was positive. The EMF could be explained by the two factors, i.e., the difference in mobilities of proton and deuteron in the electrolyte and the electrode reactions of H2 and D2 gases. The EMF of the cell for mixed isotope gases was nearly linear with the composition of hydrogen isotopes with a slight deviation and was consistent with such a mechanism of EMF of hydrogen isotope cell.

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