Electron doping of single-walled carbon nanotubes using pyridine-boryl radicals

Naoki Tanaka, Aoi Hamasuna, Takuto Uchida, Ryohei Yamaguchi, Taiki Ishii, Aleksandar Staylkov, Tsuyohiko Fujigaya

Research output: Contribution to journalArticlepeer-review

Abstract

Pyridine-boryl (py-boryl) radicals serve as efficient electron-doping reagents for single-walled carbon nanotubes (SWCNTs). The doping mechanism comprises electron transfer from the py-boryl radical to the SWCNT. The formation of a stable py-boryl cation is essential for efficient doping; the captodative effect of the py-boryl cation is important to this process.

Original languageEnglish
Pages (from-to)6019-6022
Number of pages4
JournalChemical Communications
Volume57
Issue number49
DOIs
Publication statusPublished - Jun 21 2021

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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