Electron localization and a confined electron gas in nanoporous inorganic electrides

Peter V. Sushko, Alexander L. Shluger, Katsuro Hayashi, Masahiro Hirano, Hideo Hosono

Research output: Contribution to journalArticlepeer-review

173 Citations (Scopus)

Abstract

The nanoporous main group oxide [Formula presented] (C12A7) can be transformed from a wide-gap insulator to an electride where electrons substitute anions in cages constituting a positive frame. Our ab initio calculations of the electronic structure of this novel material give a consistent explanation of its high conductivity and optical properties. They show that the electrons confined in the inert positive frame are localized in cages and undergo hopping between neighboring cages. The results are useful for the understanding of behavior of confined electron gas of different topology and electron-phonon coupling, and for designing new transparent conductors, electron emitters, and electrides.

Original languageEnglish
JournalPhysical review letters
Volume91
Issue number12
DOIs
Publication statusPublished - 2003
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

Fingerprint Dive into the research topics of 'Electron localization and a confined electron gas in nanoporous inorganic electrides'. Together they form a unique fingerprint.

Cite this