Electron-rich diplatinum(0) metallocryptate promoting novel successive encapsulation of acidic hydrides

Eri Goto, Miho Usuki, Hiroe Takenaka, Ken Sakai, Tomoaki Tanase

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12 Citations (Scopus)

Abstract

The electron-rich diplatinum (0) and dipaladium (0) complexes were synthesized to establish an 18-valence-electron configuration. The encapsulation of acidic hydrides into the cage was readily promoted, leading to the mono- and dihydride complexes. The detailed structural examination revealed the steric communication mechanism between the long-separated Pt centers. A similar mechanism was presumed to be evident in the two irreversible, suggesting that the electrochemical behavior can be switched by the stepwise hydride masking.

Original languageEnglish
Pages (from-to)6042-6051
Number of pages10
JournalOrganometallics
Volume23
Issue number25
DOIs
Publication statusPublished - Dec 6 2004
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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