Electron transfer reduction of a highly electron-deficient fullerene, C60F18

Kei Ohkubo, Roger Taylor, Olga V. Boltalina, Seiji Ogo, Shunichi Fukuzumi

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Electron transfer reduction of a highly electron-deficient fullerene, C60F18, to the defluorinated anion, C60F17- occurs efficiently by a relatively weak one-electron reductant, p-chloranil radical anion; the one-electron reduction potential of C60F18 is evaluated as 0.04 V (vs. SCE) by comparison of the rate constant for electron-transfer from 10,10′-dimethyl-9,9′,10,10′-tetrahydro-9,9′- biacridine to C60F18 with those of other one-electron reductants.

Original languageEnglish
Pages (from-to)1952-1953
Number of pages2
JournalChemical Communications
Volume8
Issue number17
DOIs
Publication statusPublished - Dec 1 2002
Externally publishedYes

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Fullerenes
Electrons
Reducing Agents
Anions
Chloranil
Negative ions
Rate constants

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Electron transfer reduction of a highly electron-deficient fullerene, C60F18 . / Ohkubo, Kei; Taylor, Roger; Boltalina, Olga V.; Ogo, Seiji; Fukuzumi, Shunichi.

In: Chemical Communications, Vol. 8, No. 17, 01.12.2002, p. 1952-1953.

Research output: Contribution to journalArticle

Ohkubo, Kei ; Taylor, Roger ; Boltalina, Olga V. ; Ogo, Seiji ; Fukuzumi, Shunichi. / Electron transfer reduction of a highly electron-deficient fullerene, C60F18 In: Chemical Communications. 2002 ; Vol. 8, No. 17. pp. 1952-1953.
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