Abstract
The electronic and infrared spectra of jet-cooled 4-aminobenzonitrile-(H2O)1 (4ABN-(H2O)1) hydrogen-bonded complex have been measured by the resonance-enhanced multiphoton ionization (REMPI) and infrared-dip (IR-dip) spectroscopy. Both the amino and cyano groups form intermolecular hydrogen bond with water, providing two stable isomers. It has been found that the substitution of the CN group at the para-position of aniline changes the electronic nature of the amino group in the S0 state from a proton acceptor to a proton donor.
| Original language | English |
|---|---|
| Pages (from-to) | 70-76 |
| Number of pages | 7 |
| Journal | Chemical Physics Letters |
| Volume | 341 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - Jun 15 2001 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
Cite this
Electronic and infrared spectra of jet-cooled 4-aminobenzonitrile- H2O . Change of NH2 from proton acceptor to proton donor by CN substitution. / Sakota, Kenji; Yamamoto, Norifumi; Ohashi, Kazuhiko; Sekiya, Hiroshi; Saeki, Morihisa; Ishiuchi, Shun Ichi; Sakai, Makoto; Fujii, Masaaki.
In: Chemical Physics Letters, Vol. 341, No. 1-2, 15.06.2001, p. 70-76.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Electronic and infrared spectra of jet-cooled 4-aminobenzonitrile- H2O . Change of NH2 from proton acceptor to proton donor by CN substitution
AU - Sakota, Kenji
AU - Yamamoto, Norifumi
AU - Ohashi, Kazuhiko
AU - Sekiya, Hiroshi
AU - Saeki, Morihisa
AU - Ishiuchi, Shun Ichi
AU - Sakai, Makoto
AU - Fujii, Masaaki
PY - 2001/6/15
Y1 - 2001/6/15
N2 - The electronic and infrared spectra of jet-cooled 4-aminobenzonitrile-(H2O)1 (4ABN-(H2O)1) hydrogen-bonded complex have been measured by the resonance-enhanced multiphoton ionization (REMPI) and infrared-dip (IR-dip) spectroscopy. Both the amino and cyano groups form intermolecular hydrogen bond with water, providing two stable isomers. It has been found that the substitution of the CN group at the para-position of aniline changes the electronic nature of the amino group in the S0 state from a proton acceptor to a proton donor.
AB - The electronic and infrared spectra of jet-cooled 4-aminobenzonitrile-(H2O)1 (4ABN-(H2O)1) hydrogen-bonded complex have been measured by the resonance-enhanced multiphoton ionization (REMPI) and infrared-dip (IR-dip) spectroscopy. Both the amino and cyano groups form intermolecular hydrogen bond with water, providing two stable isomers. It has been found that the substitution of the CN group at the para-position of aniline changes the electronic nature of the amino group in the S0 state from a proton acceptor to a proton donor.
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U2 - 10.1016/S0009-2614(01)00463-8
DO - 10.1016/S0009-2614(01)00463-8
M3 - Article
AN - SCOPUS:0002487407
VL - 341
SP - 70
EP - 76
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 1-2
ER -