Electronic and vibrational spectra of aniline-benzene hetero-dimer and aniline homo-dimer ions

Kazuhiko Ohashi, Yoshiya Inokuchi, Hironobu Izutsu, Kazuyuki Hino, Norifumi Yamamoto, Nobuyuki Nishi, Hiroshi Sekiya

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

Structures of (aniline-benzene)+ and (aniline)2+ are re-investigated by electronic spectroscopy in the near-infrared region and vibrational spectroscopy in the NH stretching region. The spectra of (aniline-benzene)+ indicate a structure including a hydrogen bond between an NH bond of the ionic aniline and the π-electrons of the neutral benzene. Two isomers are suggested for (aniline)2+ in which an NH bond of the ionic aniline forms different types of hydrogen bond with the neutral aniline: one with the π-electrons of the aromatic ring and the other with the lone pair of the nitrogen atom.

Original languageEnglish
Pages (from-to)43-48
Number of pages6
JournalChemical Physics Letters
Volume323
Issue number1-2
DOIs
Publication statusPublished - Jun 9 2000

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Vibrational spectra
Benzene
aniline
electronic spectra
Dimers
vibrational spectra
benzene
dimers
Ions
ions
Hydrogen bonds
hydrogen bonds
Vibrational spectroscopy
Electrons
Isomers
nitrogen atoms
spectroscopy
Stretching
electrons
Nitrogen

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Electronic and vibrational spectra of aniline-benzene hetero-dimer and aniline homo-dimer ions. / Ohashi, Kazuhiko; Inokuchi, Yoshiya; Izutsu, Hironobu; Hino, Kazuyuki; Yamamoto, Norifumi; Nishi, Nobuyuki; Sekiya, Hiroshi.

In: Chemical Physics Letters, Vol. 323, No. 1-2, 09.06.2000, p. 43-48.

Research output: Contribution to journalArticle

Ohashi, Kazuhiko ; Inokuchi, Yoshiya ; Izutsu, Hironobu ; Hino, Kazuyuki ; Yamamoto, Norifumi ; Nishi, Nobuyuki ; Sekiya, Hiroshi. / Electronic and vibrational spectra of aniline-benzene hetero-dimer and aniline homo-dimer ions. In: Chemical Physics Letters. 2000 ; Vol. 323, No. 1-2. pp. 43-48.
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AU - Sekiya, Hiroshi

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