Electronic states of the manganese dimer ion probed by photodissociation spectroscopy

Akira Terasaki, Akira Matsushita, Kensuke Tono, Ramkuber T. Yadav, Tina M. Briere, Tamotsu Kondow

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

The measurement of the photodissociation action spectrum in the photon energy range was used to obtain the optical spectrum of the manganese dimer ion. The density functional theory and the nonlocal corrections were used to analyze the electronic and geometric structures of the spectrum. The observed optical spectrum is consistent with the ferromagnetic spin coupling in the manganese ion where all of the 3d electrons are in the spin up state leading to an extremely large spin magnetic moment.

Original languageEnglish
Pages (from-to)9367-9370
Number of pages4
JournalJournal of Chemical Physics
Volume114
Issue number21
DOIs
Publication statusPublished - Jun 1 2001

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Photodissociation
Electronic states
Manganese
Dimers
photodissociation
manganese
dimers
Spectroscopy
Ions
optical spectrum
Magnetic moments
electronics
spectroscopy
Density functional theory
manganese ions
ions
Photons
Electrons
magnetic moments
density functional theory

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Electronic states of the manganese dimer ion probed by photodissociation spectroscopy. / Terasaki, Akira; Matsushita, Akira; Tono, Kensuke; Yadav, Ramkuber T.; Briere, Tina M.; Kondow, Tamotsu.

In: Journal of Chemical Physics, Vol. 114, No. 21, 01.06.2001, p. 9367-9370.

Research output: Contribution to journalArticle

Terasaki, A, Matsushita, A, Tono, K, Yadav, RT, Briere, TM & Kondow, T 2001, 'Electronic states of the manganese dimer ion probed by photodissociation spectroscopy', Journal of Chemical Physics, vol. 114, no. 21, pp. 9367-9370. https://doi.org/10.1063/1.1330210
Terasaki, Akira ; Matsushita, Akira ; Tono, Kensuke ; Yadav, Ramkuber T. ; Briere, Tina M. ; Kondow, Tamotsu. / Electronic states of the manganese dimer ion probed by photodissociation spectroscopy. In: Journal of Chemical Physics. 2001 ; Vol. 114, No. 21. pp. 9367-9370.
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