Electrooxidative copolymerization of 3,4-Ethylenedioxithiophene and benzene from a mixture of each monomer

Eisaku Tanaka, Hiroyuki Tateno, Yoshimasa Matsumura, Koji Nakabayashi, Izuru Kawamura, Mahito Atobe

Research output: Contribution to journalArticle

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Abstract

Electrooxidative copolymerization of 3,4-ethylenedioxithiophene (EDOT) and benzene from a mixture of the monomers with concentrations of 5mM EDOT and 5M benzene produced copolymer films on an anode surface. The formation of copolymer films and characterization of their electrochemical properties was confirmed using Fourier transform infrared (FTIR) spectroscopy, ultravioletvisible absorption (UVvis) spectroscopy, energy dispersive X-ray (EDX) spectroscopy, cyclic voltammetry (CV), and solid-state carbon-13 nuclear magnetic resonance (13CNMR) spectroscopy measurements. Furthermore, the copolymerization ratio could be controlled by selection of the oxidation potential applied for copolymerization.

Original languageEnglish
Pages (from-to)141-146
Number of pages6
JournalBulletin of the Chemical Society of Japan
Volume91
Issue number2
DOIs
Publication statusPublished - Jan 1 2018

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Benzene
Copolymerization
Monomers
Copolymers
Electrochemical properties
Absorption spectroscopy
Nuclear magnetic resonance spectroscopy
Cyclic voltammetry
Anodes
Carbon
Oxidation

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Electrooxidative copolymerization of 3,4-Ethylenedioxithiophene and benzene from a mixture of each monomer. / Tanaka, Eisaku; Tateno, Hiroyuki; Matsumura, Yoshimasa; Nakabayashi, Koji; Kawamura, Izuru; Atobe, Mahito.

In: Bulletin of the Chemical Society of Japan, Vol. 91, No. 2, 01.01.2018, p. 141-146.

Research output: Contribution to journalArticle

Tanaka, Eisaku ; Tateno, Hiroyuki ; Matsumura, Yoshimasa ; Nakabayashi, Koji ; Kawamura, Izuru ; Atobe, Mahito. / Electrooxidative copolymerization of 3,4-Ethylenedioxithiophene and benzene from a mixture of each monomer. In: Bulletin of the Chemical Society of Japan. 2018 ; Vol. 91, No. 2. pp. 141-146.
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