Electrophilic Cleavage of One Silicon-Carbon Bond of Pentacoordinate Tetraorganosilanes: Synthesis of Silalactones

Mitsuru Shindo, Kenji Matsumoto, Kozo Shishido

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Dealkylation of trialkylvinylsilanes: The direct electrophilic cleavage of one silicon-carbon bond of tetraorganosilanes activated by the intramolecular pentacoordination of a slightly nucleophilic ester or carboxylic acid group provides a novel route to silalactones (see scheme).

Original languageEnglish
Pages (from-to)104-106
Number of pages3
JournalAngewandte Chemie - International Edition
Volume43
Issue number1
DOIs
Publication statusPublished - Dec 22 2004
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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