Abstract
The inapplicability of the DLVO theory to multilayered anionic bilayers is found in terms of the co-ion-valence dependence of the lamellar repeat distance. Most of the added salt is expelled from the interlamellar space to the bulk due to the Gibbs-Donnan effect on multiple bilayers with the bulk. The electrostatic double-layer interaction is well expressed by the formula recently proposed by Trefalt. The osmotic pressure due to the expelled ions, rather than the van der Waals interaction, is the main origin of the attractive force between the bilayers.
| Original language | English |
|---|---|
| Article number | 040601 |
| Journal | Physical Review E |
| Volume | 96 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Oct 19 2017 |
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All Science Journal Classification (ASJC) codes
- Statistical and Nonlinear Physics
- Statistics and Probability
- Condensed Matter Physics
Cite this
Electrostatic double-layer interaction between stacked charged bilayers. / Hishida, Mafumi; Nomura, Yoko; Akiyama, Ryo; Yamamura, Yasuhisa; Saito, Kazuya.
In: Physical Review E, Vol. 96, No. 4, 040601, 19.10.2017.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Electrostatic double-layer interaction between stacked charged bilayers
AU - Hishida, Mafumi
AU - Nomura, Yoko
AU - Akiyama, Ryo
AU - Yamamura, Yasuhisa
AU - Saito, Kazuya
PY - 2017/10/19
Y1 - 2017/10/19
N2 - The inapplicability of the DLVO theory to multilayered anionic bilayers is found in terms of the co-ion-valence dependence of the lamellar repeat distance. Most of the added salt is expelled from the interlamellar space to the bulk due to the Gibbs-Donnan effect on multiple bilayers with the bulk. The electrostatic double-layer interaction is well expressed by the formula recently proposed by Trefalt. The osmotic pressure due to the expelled ions, rather than the van der Waals interaction, is the main origin of the attractive force between the bilayers.
AB - The inapplicability of the DLVO theory to multilayered anionic bilayers is found in terms of the co-ion-valence dependence of the lamellar repeat distance. Most of the added salt is expelled from the interlamellar space to the bulk due to the Gibbs-Donnan effect on multiple bilayers with the bulk. The electrostatic double-layer interaction is well expressed by the formula recently proposed by Trefalt. The osmotic pressure due to the expelled ions, rather than the van der Waals interaction, is the main origin of the attractive force between the bilayers.
UR - http://www.scopus.com/inward/record.url?scp=85032020450&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85032020450&partnerID=8YFLogxK
U2 - 10.1103/PhysRevE.96.040601
DO - 10.1103/PhysRevE.96.040601
M3 - Article
AN - SCOPUS:85032020450
VL - 96
JO - Physical Review E
JF - Physical Review E
SN - 2470-0045
IS - 4
M1 - 040601
ER -