Emission characteristics of F- ions into vacuum from CaF2

Takaaki Sakai, Atsushi Kaimai, Takanori Otake, Keiji Yashiro, Tatsuya Kawada, Junichiro Mizusaki, Masateru Nishioka

Research output: Contribution to journalArticle

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Abstract

Ion emission characteristics from a fluoride ionic conductor were investigated using CaF2 single crystals. The emission of F- ions was confirmed by using a quadrupole mass spectrometer, when a positive electric field was applied to the emission surface of the samples under gas pressure around 10- 3 Pa at 1173 K. Mass spectrometry also revealed that the negative ions emitted from CaF2 contained a certain amount of O- ions. It can possibly be explained that the surface of CaF2 was oxidized in the sample preparation. The emission current from CaF2 also decreased with the passage of time and increased with applied voltage and temperature. The applied voltage dependence of the emission current did not follow the Schottky equation. In Arrhenius plots, two regions with different slopes were observed, suggesting that there are two ion emission mechanisms with different activation energies.

Original languageEnglish
Pages (from-to)1601-1605
Number of pages5
JournalSolid State Ionics
Volume177
Issue number19-25 SPEC. ISS.
DOIs
Publication statusPublished - Oct 15 2006

Fingerprint

Vacuum
Ions
vacuum
ion emission
ions
Arrhenius plots
Electric potential
electric potential
Mass spectrometers
Fluorides
negative ions
mass spectrometers
gas pressure
Mass spectrometry
fluorides
Negative ions
mass spectroscopy
conductors
Activation energy
quadrupoles

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Sakai, T., Kaimai, A., Otake, T., Yashiro, K., Kawada, T., Mizusaki, J., & Nishioka, M. (2006). Emission characteristics of F- ions into vacuum from CaF2. Solid State Ionics, 177(19-25 SPEC. ISS.), 1601-1605. https://doi.org/10.1016/j.ssi.2006.05.014

Emission characteristics of F- ions into vacuum from CaF2. / Sakai, Takaaki; Kaimai, Atsushi; Otake, Takanori; Yashiro, Keiji; Kawada, Tatsuya; Mizusaki, Junichiro; Nishioka, Masateru.

In: Solid State Ionics, Vol. 177, No. 19-25 SPEC. ISS., 15.10.2006, p. 1601-1605.

Research output: Contribution to journalArticle

Sakai, T, Kaimai, A, Otake, T, Yashiro, K, Kawada, T, Mizusaki, J & Nishioka, M 2006, 'Emission characteristics of F- ions into vacuum from CaF2', Solid State Ionics, vol. 177, no. 19-25 SPEC. ISS., pp. 1601-1605. https://doi.org/10.1016/j.ssi.2006.05.014
Sakai T, Kaimai A, Otake T, Yashiro K, Kawada T, Mizusaki J et al. Emission characteristics of F- ions into vacuum from CaF2. Solid State Ionics. 2006 Oct 15;177(19-25 SPEC. ISS.):1601-1605. https://doi.org/10.1016/j.ssi.2006.05.014
Sakai, Takaaki ; Kaimai, Atsushi ; Otake, Takanori ; Yashiro, Keiji ; Kawada, Tatsuya ; Mizusaki, Junichiro ; Nishioka, Masateru. / Emission characteristics of F- ions into vacuum from CaF2. In: Solid State Ionics. 2006 ; Vol. 177, No. 19-25 SPEC. ISS. pp. 1601-1605.
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