Emulsion Droplets Stabilized by Close-Packed Janus Regular Polygonal Particles

Ryotaro Koike, Yasutaka Iwashita, Yasuyuki Kimura

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

In Pickering-Ramsden emulsions, the packing structure of the colloidal particles at the liquid-liquid (or liquid-gas) interface significantly affects the structure and behavior of the emulsion. Here, using a series of platelike particles with regular polygonal shapes and Janus amphiphilicity, we created emulsion droplets stabilized by close-packed polygonal particles at the interface. The systematic variation of the particle morphology shows that the geometrical features of the regular polygons in (curved) planar packing dominate over the self-assembled structures. The structures are tessellations of triangular, square, and hexagonal particles at the surface for large droplets and regular tetrahedral, cubic, and dodecahedral particle shells of triangular, square, and pentagonal particles for small droplets, respectively. This work creates the possibility of geometrically designing the structure and functionality of emulsions.

Original languageEnglish
Pages (from-to)12394-12400
Number of pages7
JournalLangmuir
Volume34
Issue number41
DOIs
Publication statusPublished - Oct 16 2018

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All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

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