Abstract
(Salen)manganese(III) complex 5 [2,2′-[2-methylpropane-1,2-diylbis (nitrilomethylidyne)]-5,5′ - dimethyl-6,6′ - (1-phenylpropyl)diphenolatomanganese (III)] bearing one set of stereogenic centers in the 1-phenylpropyl substituents and a geminally dimethylated ethylenediamine moiety was found to catalyze the enantioselective epoxidation of E olefins just as effectively as the reported (salen)manganese(III) complex 2, which bears two sets of stereogenic centers, in the ring substituents and on the ethylenediamine moiety.
| Original language | English |
|---|---|
| Pages (from-to) | 691-692 |
| Number of pages | 2 |
| Journal | Synlett |
| Volume | 1991 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - Jan 1 1991 |
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All Science Journal Classification (ASJC) codes
- Organic Chemistry
Cite this
Enantioselective epoxidation of olefins with chiral (salen)manganese(III) complexes bearing 4-methyl-3-[(R)-1-phenylpropyl]salicylideneamine as a constituent. / Hosoya, Naoki; Irie, Ryo; Ito, Yoshio; Katsuki, Tsutomu.
In: Synlett, Vol. 1991, No. 10, 01.01.1991, p. 691-692.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Enantioselective epoxidation of olefins with chiral (salen)manganese(III) complexes bearing 4-methyl-3-[(R)-1-phenylpropyl]salicylideneamine as a constituent
AU - Hosoya, Naoki
AU - Irie, Ryo
AU - Ito, Yoshio
AU - Katsuki, Tsutomu
PY - 1991/1/1
Y1 - 1991/1/1
N2 - (Salen)manganese(III) complex 5 [2,2′-[2-methylpropane-1,2-diylbis (nitrilomethylidyne)]-5,5′ - dimethyl-6,6′ - (1-phenylpropyl)diphenolatomanganese (III)] bearing one set of stereogenic centers in the 1-phenylpropyl substituents and a geminally dimethylated ethylenediamine moiety was found to catalyze the enantioselective epoxidation of E olefins just as effectively as the reported (salen)manganese(III) complex 2, which bears two sets of stereogenic centers, in the ring substituents and on the ethylenediamine moiety.
AB - (Salen)manganese(III) complex 5 [2,2′-[2-methylpropane-1,2-diylbis (nitrilomethylidyne)]-5,5′ - dimethyl-6,6′ - (1-phenylpropyl)diphenolatomanganese (III)] bearing one set of stereogenic centers in the 1-phenylpropyl substituents and a geminally dimethylated ethylenediamine moiety was found to catalyze the enantioselective epoxidation of E olefins just as effectively as the reported (salen)manganese(III) complex 2, which bears two sets of stereogenic centers, in the ring substituents and on the ethylenediamine moiety.
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UR - http://www.scopus.com/inward/citedby.url?scp=84989586126&partnerID=8YFLogxK
U2 - 10.1055/s-1991-34756
DO - 10.1055/s-1991-34756
M3 - Article
AN - SCOPUS:84989586126
VL - 1991
SP - 691
EP - 692
JO - Synlett
JF - Synlett
SN - 0936-5214
IS - 10
ER -