Enantioselective epoxidation of olefins with chiral (salen)manganese(III) complexes bearing 4-methyl-3-[(R)-1-phenylpropyl]salicylideneamine as a constituent

Naoki Hosoya, Ryo Irie, Yoshio Ito, Tsutomu Katsuki

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

(Salen)manganese(III) complex 5 [2,2′-[2-methylpropane-1,2-diylbis (nitrilomethylidyne)]-5,5′ - dimethyl-6,6′ - (1-phenylpropyl)diphenolatomanganese (III)] bearing one set of stereogenic centers in the 1-phenylpropyl substituents and a geminally dimethylated ethylenediamine moiety was found to catalyze the enantioselective epoxidation of E olefins just as effectively as the reported (salen)manganese(III) complex 2, which bears two sets of stereogenic centers, in the ring substituents and on the ethylenediamine moiety.

Original languageEnglish
Pages (from-to)691-692
Number of pages2
JournalSynlett
Volume1991
Issue number10
DOIs
Publication statusPublished - Jan 1 1991

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ethylenediamine
Bearings (structural)
Epoxidation
Alkenes
Manganese
disalicylaldehyde ethylenediamine

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

Enantioselective epoxidation of olefins with chiral (salen)manganese(III) complexes bearing 4-methyl-3-[(R)-1-phenylpropyl]salicylideneamine as a constituent. / Hosoya, Naoki; Irie, Ryo; Ito, Yoshio; Katsuki, Tsutomu.

In: Synlett, Vol. 1991, No. 10, 01.01.1991, p. 691-692.

Research output: Contribution to journalArticle

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