Enantioselective epoxidation of olefins with chiral (Salen)manganese(III) complexes bearing 4-Methyl-3-[(R)-l-phenylpropyl] salicylideneamine as a constituent

Naoki Hosoya, Ryo Ine, Yoshio Ito, Tsutomu Katsuki

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Abstract

(Salen)manganese(III) complex 5 [2, 2′-[2-methylpropa-ne-li-diylbis(nitrilomethylidyne)]-5, 5′- dimethyl-6, 6′- (1-phenyl-propyl)diphenolatomanganese(III)] bearing one set of stereogenic centers in the 1-phenylpropyl substituents and a geminally dimethylated ethylenediamine moiety was found to catalyze the enantioselective epoxidation of olefins just as effectively as the reported (salen)manganese(III) complex 2, which bears two sets of stereogenic centers, in the ring substituents and on the ethylenediamine moiety.

Original languageEnglish
Pages (from-to)691-692
Number of pages2
JournalSynlett
Volume1991
Issue number10
DOIs
Publication statusPublished - Jan 1 1991

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ethylenediamine
Bearings (structural)
Epoxidation
Alkenes
Manganese
disalicylaldehyde ethylenediamine

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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Enantioselective epoxidation of olefins with chiral (Salen)manganese(III) complexes bearing 4-Methyl-3-[(R)-l-phenylpropyl] salicylideneamine as a constituent. / Hosoya, Naoki; Ine, Ryo; Ito, Yoshio; Katsuki, Tsutomu.

In: Synlett, Vol. 1991, No. 10, 01.01.1991, p. 691-692.

Research output: Contribution to journalArticle

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