Encapsulated molecular catalysts in polysiloxane gels: Ruthenium cluster-catalyzed isomerization of alkenes

Yukihiro Motoyama; Motonori Abe; Kazuyuki Kamo; Yusuke Kosako; Hideo Nagashima

doi:10.1039/b809937e

Encapsulated molecular catalysts in polysiloxane gels: Ruthenium cluster-catalyzed isomerization of alkenes

Yukihiro Motoyama, Motonori Abe, Kazuyuki Kamo, Yusuke Kosako, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Novel ruthenium-encapsulating polysiloxane gels are prepared by treatment of polymethylhydrosiloxane with diols in the presence of (μ₃, η²,η³,η⁵-acenaphthylene)Ru ₃(CO)₇, and act as reusable catalysts in the isomerization of alkenes without leakage of the catalyst species.

Original language	English
Pages (from-to)	5321-5323
Number of pages	3
Journal	Chemical Communications
Issue number	42
DOIs	https://doi.org/10.1039/b809937e
Publication status	Published - 2008

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Novel ruthenium-encapsulating polysiloxane gels are prepared by treatment of polymethylhydrosiloxane with diols in the presence of (μ3, η2,η3,η5-acenaphthylene)Ru 3(CO)7, and act as reusable catalysts in the isomerization of alkenes without leakage of the catalyst species.",

author = "Yukihiro Motoyama and Motonori Abe and Kazuyuki Kamo and Yusuke Kosako and Hideo Nagashima",

year = "2008",

doi = "10.1039/b809937e",

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T1 - Encapsulated molecular catalysts in polysiloxane gels

T2 - Ruthenium cluster-catalyzed isomerization of alkenes

AU - Motoyama, Yukihiro

AU - Abe, Motonori

AU - Kamo, Kazuyuki

AU - Kosako, Yusuke

AU - Nagashima, Hideo

PY - 2008

Y1 - 2008

N2 - Novel ruthenium-encapsulating polysiloxane gels are prepared by treatment of polymethylhydrosiloxane with diols in the presence of (μ3, η2,η3,η5-acenaphthylene)Ru 3(CO)7, and act as reusable catalysts in the isomerization of alkenes without leakage of the catalyst species.

AB - Novel ruthenium-encapsulating polysiloxane gels are prepared by treatment of polymethylhydrosiloxane with diols in the presence of (μ3, η2,η3,η5-acenaphthylene)Ru 3(CO)7, and act as reusable catalysts in the isomerization of alkenes without leakage of the catalyst species.

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JO - Chemical Communications

JF - Chemical Communications

IS - 42

ER -

Encapsulated molecular catalysts in polysiloxane gels: Ruthenium cluster-catalyzed isomerization of alkenes

Abstract

All Science Journal Classification (ASJC) codes

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