Enhanced bistability by guest inclusion in Fe(II) spin crossover porous coordination polymers

Francisco J.Muñoz Lara, Ana B. Gaspar, Daniel Aravena, Eliseo Ruiz, M. Carmen Muñoz, Kouhei Tsumoto, Ryo Ohtani, Susumu Kitagawa, José A. Real

Research output: Contribution to journalArticlepeer-review

86 Citations (Scopus)

Abstract

Inclusion of thiourea guest molecules in the tridimensional spin crossover porous coordination polymers ([Fe(pyrazine)[M(CN)4]) (M = Pd, Pt) leads to novel clathrates exhibiting unprecedented large thermal hysteresis loops of ca. 60 K wide centered near room temperature.

Original languageEnglish
Pages (from-to)4686-4688
Number of pages3
JournalChemical Communications
Volume48
Issue number39
DOIs
Publication statusPublished - Apr 18 2012
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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