Enhanced Electroluminescence from a Thiophene-Based Insulated Molecular Wire

Gábor Méhes, Chengjun Pan, Fatima Bencheikh, Li Zhao, Kazunori Sugiyasu, Masayuki Takeuchi, Jean Charles Maurice Ribierre, Chihaya Adachi

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

We report on the realization of polymer light-emitting diodes (PLEDs) based on fluorescent polythiophene (PT)-based insulated molecular wires (IMWs). PLEDs using PT emitting layers traditionally have low external quantum efficiencies (ηeqe) below 0.1%. Moreover, IMWs lack a thorough exploitation for electroluminescent applications due to concerns about reduced charge transport between their chains. We constructed multilayer PLEDs containing PT IMW emitting layers that show the maximum ηeqe close to 1.4%, luminance at 3700 cd/m2, and low turn on voltage at 2.5 V. We also show a strong influence of the thickness of electron transport layer on ηeqe through device optimization and optical simulations.

Original languageEnglish
Pages (from-to)781-785
Number of pages5
JournalACS Macro Letters
Volume5
Issue number7
DOIs
Publication statusPublished - Jul 19 2016

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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  • Cite this

    Méhes, G., Pan, C., Bencheikh, F., Zhao, L., Sugiyasu, K., Takeuchi, M., Ribierre, J. C. M., & Adachi, C. (2016). Enhanced Electroluminescence from a Thiophene-Based Insulated Molecular Wire. ACS Macro Letters, 5(7), 781-785. https://doi.org/10.1021/acsmacrolett.6b00205