Enhanced Light–Matter Interaction and Polariton Relaxation by the Control of Molecular Orientation

Tomohiro Ishii, Fatima Bencheikh, Sébastien Forget, Sébastien Chénais, Benoît Heinrich, David Kreher, Lydia Sosa Vargas, Kiyoshi Miyata, Ken Onda, Takashi Fujihara, Stéphane Kéna-Cohen, Fabrice Mathevet, Chihaya Adachi

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Exciton-polaritons, in which the electronic state of an excited organic molecule and a photonic state are strongly coupled, can form a Bose–Einstein condensate (BEC) at room temperature. However, so far, the reported thresholds of organic polariton BECs under optical excitation are as high as Pth = 11–500 μJ cm–2. One route toward lowering the condensation threshold is to increase the Rabi energy by aligning the molecular transition dipole moments. In this report, it is demonstrated that control of the orientation of a perylene-based discotic dye, which is able to self-organize in mesogenic columnar structures, can significantly enhance exciton–photon interaction and polariton relaxation rate in optical cavities. These results show the importance of the molecular orientation for strong light–matter interactions and provide a promising strategy toward the realization of an organic low threshold polariton BEC system and electrically driven organic polariton BEC.

Original languageEnglish
Article number2101048
JournalAdvanced Optical Materials
Volume9
Issue number22
DOIs
Publication statusPublished - Nov 18 2021

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics

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