Enhanced performance of yolk-shell structured Si-PPy composite as an anode for lithium ion batteries

Zhen Liu, Yuwen Luo, Mingjiong Zhou, Wenqin Wang, Ning Gan, Shigeto Okada, Jun Ichi Yamaki

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Yolk-shell structured silicon-polypyrrole (Si-PPy) composite has been prepared by an in situ chemical polymerization approach. The designed parcel method significantly improves the cycling stability and rate capability compared to those of bare silicon. The Si-PPy composite exhibits a high specific capacity of 1400mAhg-1 after 100 cycles, which is approximately 4 times higher than bare Si. Moreover, the Si-PPy composite delivers a high reversible capacity of ∼1200mAhg-1 at a high current density of 10Ag-1, while the bare Si only achieves a low capacity of ∼490mAhg-1 at the same current density. The outstanding electrochemical properties of the Si-PPy composites are attributed to the stability and conductivity of the PPy shell and the nanoscale structure of the composite.

Original languageEnglish
Pages (from-to)1067-1070
Number of pages4
JournalElectrochemistry
Volume83
Issue number12
DOIs
Publication statusPublished - Jan 1 2015

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All Science Journal Classification (ASJC) codes

  • Electrochemistry

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