Enhanced reactivity of hydrophobic vitamin B12 towards the dechlorination of DDT in ionic liquid

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

The electrolytic reductive dechlorination of 1,1-bis(p-chlorophenyl)-2,2,2- trichloroethane (DDT) in the ionic liquid (IL) 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) in the presence of a cobalamin derivative afforded 1,1′-(ethylidene)bis(4-chlorobenzene) (DDO) and 1,1′-(ethenylidene)bis(4-chlorobenzene) (DDNU) with 1,1′-(2- chloroethylidene)bis(4-chlorobenzene) (DDMS); the enhanced reactivity, as well as the recyclability of the cobalamin derivative catalyst in IL, makes the present system more efficient for the development of "green" technologies.

Original languageEnglish
Pages (from-to)1653-1655
Number of pages3
JournalChemical Communications
Issue number16
DOIs
Publication statusPublished - May 31 2007

Fingerprint

Ionic Liquids
Dechlorination
DDT
Vitamins
Vitamin B 12
Ionic liquids
Environmental technology
Derivatives
Catalysts
chlorobenzene

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Enhanced reactivity of hydrophobic vitamin B12 towards the dechlorination of DDT in ionic liquid. / Jabbar, Md Abdul; Shimakoshi, Hisashi; Hisaeda, Yoshio.

In: Chemical Communications, No. 16, 31.05.2007, p. 1653-1655.

Research output: Contribution to journalArticle

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