Enhancement effect on the chemiluminescence of acridinium esters under neutral conditions

Manabu Nakazono, Shinkoh Nanbu

Research output: Contribution to journalArticle

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Abstract

Enhancement effect on the chemiluminescence of acridinium ester derivatives under neutral conditions was investigated. Additions of phenols did not enhance the chemiluminescence intensities of acridinium ester derivatives in the presence of horseradish peroxidase and hydrogen peroxide. Additions of cetyltrimethylammonium bromide apparently enhanced the chemiluminescence intensities of phenyl 10-methyl-10λ4-acridine-9-carboxylate derivatives with electron-withdrawing groups at the 4-position of the phenyl group. In particular, the chemiluminescence intensity of 4-(trifluoromethyl)phenyl 10-methyl-10λ4-acridine-9-carboxylate trifluoromethanesulfonate salt was 5.5 times stronger in the presence of cetyltrimethylammonium bromide than in its absence at pH 7. The chemiluminescence intensity of 3,4-dicyano-phenyl 10-methyl-10λ4-acridine-9-carboxylate trifluoromethanesulfonate salt was 46 times stronger in the presence of cetyltrimethylammonium bromide at pH 7 than in its absence at pH 10.

Original languageEnglish
Pages (from-to)345-348
Number of pages4
JournalLuminescence
Volume33
Issue number2
DOIs
Publication statusPublished - Mar 1 2018

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Chemiluminescence
Luminescence
Esters
Acridines
Derivatives
Salts
Phenols
Horseradish Peroxidase
Hydrogen Peroxide
Electrons
cetrimonium

All Science Journal Classification (ASJC) codes

  • Biophysics
  • Chemistry (miscellaneous)

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Enhancement effect on the chemiluminescence of acridinium esters under neutral conditions. / Nakazono, Manabu; Nanbu, Shinkoh.

In: Luminescence, Vol. 33, No. 2, 01.03.2018, p. 345-348.

Research output: Contribution to journalArticle

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