Enhancement of discrimination ability for cis- and trans-decalins through side-chain ordering in comb-shaped polymer

Atsuomi Shundo; Abul K. Mallik; Hisaki Nakashima; Makoto Takafuji; Shoji Nagaoka; M. A.Jamil Chowdhury; Hirotaka Ihara

doi:10.1246/cl.2010.844

Enhancement of discrimination ability for cis- and trans-decalins through side-chain ordering in comb-shaped polymer

Atsuomi Shundo, Abul K. Mallik, Hisaki Nakashima, Makoto Takafuji, Shoji Nagaoka, M. A.Jamil Chowdhury, Hirotaka Ihara

Research output: Contribution to journal › Review article › peer-review

2 Citations (Scopus)

Abstract

We propose poly(octadecyl acrylate), ODA., as a host polymer for discriminating cis- and trans-decalins. Liquid chromatographic method enabled to detect a thermally induced change in selectivity and enhanced selectivity was achieved at lower temperature, where the side chains in ODA_n formed an ordered structure. The thermodynamic analysis for temperature-varied elution behaviors was also described.

Original language	English
Pages (from-to)	844-845
Number of pages	2
Journal	Chemistry Letters
Volume	39
Issue number	8
DOIs	https://doi.org/10.1246/cl.2010.844
Publication status	Published - 2010
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2010.844

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abstract = "We propose poly(octadecyl acrylate), ODA., as a host polymer for discriminating cis- and trans-decalins. Liquid chromatographic method enabled to detect a thermally induced change in selectivity and enhanced selectivity was achieved at lower temperature, where the side chains in ODAn formed an ordered structure. The thermodynamic analysis for temperature-varied elution behaviors was also described.",

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AU - Shundo, Atsuomi

AU - Mallik, Abul K.

AU - Nakashima, Hisaki

AU - Takafuji, Makoto

AU - Nagaoka, Shoji

AU - Chowdhury, M. A.Jamil

AU - Ihara, Hirotaka

PY - 2010

Y1 - 2010

N2 - We propose poly(octadecyl acrylate), ODA., as a host polymer for discriminating cis- and trans-decalins. Liquid chromatographic method enabled to detect a thermally induced change in selectivity and enhanced selectivity was achieved at lower temperature, where the side chains in ODAn formed an ordered structure. The thermodynamic analysis for temperature-varied elution behaviors was also described.

AB - We propose poly(octadecyl acrylate), ODA., as a host polymer for discriminating cis- and trans-decalins. Liquid chromatographic method enabled to detect a thermally induced change in selectivity and enhanced selectivity was achieved at lower temperature, where the side chains in ODAn formed an ordered structure. The thermodynamic analysis for temperature-varied elution behaviors was also described.

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U2 - 10.1246/cl.2010.844

DO - 10.1246/cl.2010.844

M3 - Review article

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JO - Chemistry Letters

JF - Chemistry Letters

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ER -

Enhancement of discrimination ability for cis- and trans-decalins through side-chain ordering in comb-shaped polymer

Abstract

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