Enhancement of discrimination ability for cis- and trans-decalins through side-chain ordering in comb-shaped polymer

Atsuomi Shundo, Abul K. Mallik, Hisaki Nakashima, Makoto Takafuji, Shoji Nagaoka, M. A.Jamil Chowdhury, Hirotaka Ihara

Research output: Contribution to journalReview article

1 Citation (Scopus)

Abstract

We propose poly(octadecyl acrylate), ODA., as a host polymer for discriminating cis- and trans-decalins. Liquid chromatographic method enabled to detect a thermally induced change in selectivity and enhanced selectivity was achieved at lower temperature, where the side chains in ODAn formed an ordered structure. The thermodynamic analysis for temperature-varied elution behaviors was also described.

Original languageEnglish
Pages (from-to)844-845
Number of pages2
JournalChemistry Letters
Volume39
Issue number8
DOIs
Publication statusPublished - 2010
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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  • Cite this

    Shundo, A., Mallik, A. K., Nakashima, H., Takafuji, M., Nagaoka, S., Chowdhury, M. A. J., & Ihara, H. (2010). Enhancement of discrimination ability for cis- and trans-decalins through side-chain ordering in comb-shaped polymer. Chemistry Letters, 39(8), 844-845. https://doi.org/10.1246/cl.2010.844