Enhancement of fluorescence in colloidal CuInS2 nanocrystals by introduction of crystal defect

Masato Uehara, Kosuke Watanabe, Yasuyuki Tajiri, Hiroyuki Nakamura, Hideaki Maeda

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    Cu-In-S nanocrystals were developed as a low toxic fluorescent. The stoichiometric CuInS2 nanocrystals were synthesized facilely by heating a solution of metal complexes. The fluorescence would be originated from the crystal defect. We intentionally introduced the crystal defects related to Cu deficiency in nanocrystal with the prospect that the fluorescence intensity would be increased. The nanocrystals have many defects without phase separation as observed in bulk material. Consequently, the fluorescence quantum yield achieved to c.a. 6%. Moreover, the fluorescence quantum yield was increased up to 15% by the ZnS-coating.

    Original languageEnglish
    Title of host publicationNanocrystalline Materials as Precursors for Complex Multifunctional Structures through Chemical Transformations and Self Assembly
    PublisherMaterials Research Society
    Pages15-19
    Number of pages5
    ISBN (Print)9781615677849
    DOIs
    Publication statusPublished - 2009
    Event2009 MRS Spring Meeting - San Francisco, CA, United States
    Duration: Apr 14 2009Apr 17 2009

    Publication series

    NameMaterials Research Society Symposium Proceedings
    Volume1176
    ISSN (Print)0272-9172

    Other

    Other2009 MRS Spring Meeting
    CountryUnited States
    CitySan Francisco, CA
    Period4/14/094/17/09

    All Science Journal Classification (ASJC) codes

    • Materials Science(all)
    • Condensed Matter Physics
    • Mechanics of Materials
    • Mechanical Engineering

    Fingerprint Dive into the research topics of 'Enhancement of fluorescence in colloidal CuInS<sub>2</sub> nanocrystals by introduction of crystal defect'. Together they form a unique fingerprint.

    Cite this